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1. A photoresponsive gold catalyst based on azobenzene-functionalized NHC ligands.

Author

Liu J, Bobylev EO, de Bruin B, and Reek JNH

Subjects
Ligands, Isomerism, Gold, Azo Compounds
Abstract

An azobenzene-bearing N-heterocyclic carbene-based gold catalyst is reported of which the reactivity in a cyclization reaction depends on the isomeric state of the azobenzene. The configurations of the catalyst can be reversibly switched by light and are stable during the reaction, effectively leading to a switchable catalyst system.

Published
2023
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