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Your search keyword '"Xiaotai Wang"' showing total 3 results
Start Over Author "Xiaotai Wang" Journal chemical communications (cambridge, england)
3 results on '"Xiaotai Wang"'

1. Mechanism of C-P bond formation via Pd-catalyzed decarbonylative phosphorylation of amides: insight into the chemistry of the second coordination sphere

Author

Xiaotai Wang, Wen-Yan Tong, Thu D. Ly, Tao-Tao Zhao, and Yan-Bo Wu

Subjects
Reaction mechanism, Coordination sphere, Proton, Chemistry, Hydrogen bond, Metals and Alloys, General Chemistry, Bond formation, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Mechanism (philosophy), Computational chemistry, Materials Chemistry, Ceramics and Composites, Phosphorylation
Abstract

We report on the basis of DFT computations a plausible and detailed reaction mechanism for the first Pd-catalyzed decarbonylative phosphorylation of amides forming C–P bonds, which reveals, among other things, crucial events in the second coordination sphere, including ion pair and hydrogen bonding interactions as well as proton transfer.

Published
2019

3. Novel silver(I)-organic coordination polymers: conversion of extended structures in the solid state as driven by argentophilic interactions

Author

E. Brice Woodlock, Kin-Chung Lam, Long Pan, Xiaotai Wang, and Arnold L. Rheingold

Subjects
chemistry.chemical_classification, Materials science, Metals and Alloys, Solid-state, Nanotechnology, General Chemistry, Polymer, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, chemistry.chemical_compound, chemistry, Chemical engineering, Propane, Materials Chemistry, Ceramics and Composites
Abstract

Structurally distinct coordination polymers [Ag(bpp)]ClO4 1 and [Ag(bpp)]PF6 2 [bpp = 1,3-bis(4-pyridyl)propane] have been assembled; the conversion of 1 into 2 on treatment with NaPF6 is driven by argentophilic interactions and is the first such transformation reported for silver(I)-organic coordination polymers.

Published
2002

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