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Start Over Author "James A. Town" Journal chemical communications (cambridge, england)
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1. Synthesis and [2+2]-photodimerisation of monothiomaleimide functionalised linear and brush-like polymers

Author

James S. Town, David M. Haddleton, Paul Wilson, Evelina Liarou, James R. Baker, and Mohammed Aljuaid

Subjects
chemistry.chemical_classification, Metals and Alloys, Brush, General Chemistry, Polymer, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, law.invention, Reaction rate, End-group, chemistry.chemical_compound, chemistry, law, Polymer chemistry, Materials Chemistry, Ceramics and Composites, QD, Irradiation, Acetonitrile
Abstract

[2+2]-Photodimerisation of monothiomaleimides has been demonstrated on functionalised linear and brush-like polymers. In water/acetonitrile (95 : 5) mixtures the rate of reaction is accelerated significantly by irradiation of the thiomaleimide end group (λmax = 350 nm) with UV light, reaching full conversion within 10 minutes.

Published
2020

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