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Start Over Author "Dimitri Matioszek" Journal chemical communications (cambridge, england)
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1. Phosphaalkenyl germylenes and their gold, tungsten and molybdenum complexes

Author

Dimitri Matioszek, Gabriela Nemes, Annie Castel, Nathalie Saffon, Tibor-Gabor Kocsor, and Jean Escudié

Subjects
Denticity, Chemistry, Inorganic chemistry, Metals and Alloys, chemistry.chemical_element, Germanium, General Chemistry, Tungsten, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Crystallography, Molybdenum, Phosphorus atom, Atom, Materials Chemistry, Ceramics and Composites
Abstract

The new bis(phosphaalkenyl) germanium(II) compound (NHC)Ge(CCl=PMes*)(2) reacts with L(2)M(CO)(4) (M = Mo, W) to give bidentate complexes with an unexpected coordinating behaviour involving the Ge(II) centre and one phosphorus atom, and with AuI or Me(2)SAuCl to afford the monodentate complexes coordinated at the germanium(II) atom.

Published
2012

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