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Your search keyword '"Schaak, Raymond E."' showing total 13 results
Start Over Author "Schaak, Raymond E." Journal chemical communications
13 results on '"Schaak, Raymond E."'

2. One-step topochemical transformation of MoAlB into metastable Mo2AlB2 using a metal chloride salt reaction.

Author

Baumler, Katelyn J., Adams, Owen S., and Schaak, Raymond E.

Subjects
METAL chlorides, SALT
Abstract

Reacting MoAlB with ZnCl2 at 550 °C produces metastable Mo2AlB2 through a one-step topochemical transformation. This reaction showcases differences in reactivity between boride-based MAB phases and carbide-based MAX phases, which are solid-state precursors to an important family of 2-D materials. [ABSTRACT FROM AUTHOR]

Published
2023
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12. Polyol synthesis of palladium hydride: bulk powders vs. nanocrystals.

Author

Ting-Hao Phan and Schaak, Raymond E.

Subjects
*POLYOL synthesis, *PALLADIUM compounds, *SOLUTION (Chemistry), *HYDROGEN, *NANOCRYSTALS, *TEMPERATURE effect
Abstract

Palladium is converted into palladium hydride, β-PdHx, in polyol solution using NaBH4 as a hydrogen source; nanocrystalline Pd reacts to form PdHx faster and at lower temperatures than bulk Pd, and can be made to release hydrogen to regenerate Pd. [ABSTRACT FROM AUTHOR]

Published
2009
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13. Polyol synthesis of palladium hydride: bulk powders vs.nanocrystalsElectronic supplementary information (ESI) available: Complete experimental details and GC data. See DOI: 10.1039/b902024a.

Author

Phan, Ting-Hao and Schaak, Raymond E.

Subjects
*POLYOLS, *ORGANIC synthesis, *PALLADIUM compounds, *HYDRIDES, *METAL powders, *NANOCRYSTALS, *SODIUM compounds
Abstract

Palladium is converted into palladium hydride, β-PdHx, in polyol solution using NaBH4as a hydrogen source; nanocrystalline Pd reacts to form PdHxfaster and at lower temperatures than bulk Pd, and can be made to release hydrogen to regenerate Pd. [ABSTRACT FROM AUTHOR]

Published
2009
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