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Start Over Author "Melissa A. Skidmore" Journal chemical communications
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1. Reversibility in free-radical reactions of aryltellurides with tributylstannyl radical

Author

Carl H. Schiesser and Melissa A. Skidmore

Subjects
Primary (chemistry), Chemistry, Radical, Metals and Alloys, Alkyl radicals, Tributyltin hydride, General Chemistry, Photochemistry, Catalysis, Dowd–Beckwith ring-expansion reaction, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, chemistry.chemical_compound, Materials Chemistry, Ceramics and Composites, Benzene
Abstract

119 Sn and 125Te NMR spectroscopies reveal that methyl, primary and secondary alkyl radicals, generated by reaction of phenyltelluroalkanes 4, 6, 7 with tributyltin hydride (benzene, AIBN initiator), are capable of displacing tributylstannyl radicals from (4-fluorophenyltelluro)tributylstannane to afford the 4-fluorophenyltelluroalkanes 3, 8, 9.

Published
1996
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