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Start Over Author "Jon A. Tunge" Journal chemical communications
3 results on '"Jon A. Tunge"'

1. Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling

Author

Jon A. Tunge and Shelli R. Waetzig

Subjects
Allylic rearrangement, Decarboxylation, Metals and Alloys, chemistry.chemical_element, General Chemistry, Medicinal chemistry, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Stereospecificity, chemistry, Materials Chemistry, Ceramics and Composites, Organic chemistry, Palladium
Abstract

This communication details the Pd-catalyzed decarboxylation of selenocarbonates; use of a chiral nonracemic catalyst affords enantioenriched allyl selenides which undergo stereospecific [2,3]-sigmatropic rearrangements to form enantioenriched allylic amines and chlorides.

Published
2008
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2. Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling.

Author

Shelli R. Waetzig and Jon A. Tunge

Subjects
SELENIUM compounds, INORGANIC compounds, COPPER-molybdenum-selenium alloys, SELENIDES, ORGANOSELENIUM compounds
Abstract

This communication details the Pd-catalyzed decarboxylation of selenocarbonates; use of a chiral nonracemic catalyst affords enantioenriched allyl selenides which undergo stereospecific [2,3]-sigmatropic rearrangements to form enantioenriched allylic amines and chlorides. [ABSTRACT FROM AUTHOR]

Published
2008
Full Text
View/download PDF

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