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This study explores peptide-mediated chiral induction and circularly polarized luminescence (CPL) in achiral BODIPY dyes, leading to a high glum value of up to −1.2 × 10−2 through orthogonal halogen bonding and hydrogen bonding. It unravels the impact of these combined directional interactions on the formation of heterostructures and their thermal stability. [ABSTRACT FROM AUTHOR]

The chiral spin–flip luminophore [Cr(ddpd)2]3+ can be resolved into enantiopure material by chiral HPLC. The corresponding enantiomers show very high luminescence dissymmetry factors of up to ∣glum ∣≈ 0.093 in circularly polarized luminescence (CPL) measurements for the "ruby-like" phosphorescence transition 2E/2T1 → 4A2 in the near-IR region around λ ≈ 775 nm. [ABSTRACT FROM AUTHOR]

Quinoline oligoamide foldamers appended with non-chiral fluorophores and derivatized with a camphanyl chiral inducer display strong chiroptical properties at tunable wavelengths as proved by CD and CPL spectroscopies. Induced CPL activity with high luminescence dissymmetry factors was observed in the visible range at wavelengths specific to the fluorophores. [ABSTRACT FROM AUTHOR]