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Your search keyword '"Zhu, Shou‐Fei"' showing total 1 results
Start Over Author "Zhu, Shou‐Fei" Topic hydrogenation Journal chemical communications
1 results on '"Zhu, Shou‐Fei"'

1. Enantioselective iridium-catalyzed hydrogenation of β,β-disubstituted nitroalkenes.

Author

Yu, Yan-Bo, Cheng, Lei, Li, Yi-Pan, Fu, Yue, Zhu, Shou-Fei, and Zhou, Qi-Lin

Subjects
NITROALKENES, HYDROGENATION, IRIDIUM catalysts, ENANTIOSELECTIVE catalysis, METAL complexes
Abstract

An iridium complex with a newly prepared chiral spiro amino-phosphine ligand efficiently catalyzed the hydrogenation of both β-aryl-β-methyl-nitroalkenes and β-alkyl-β-methyl-nitroalkenes to the corresponding saturated nitroalkanes, which represents the first report of a chiral catalyst that exhibits high enantioselectivity for the challenging hydrogenation of β,β-dialkyl-nitroalkenes. [ABSTRACT FROM AUTHOR]

Published
2016
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