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Your search keyword '"Zhu, Shou‐Fei"' showing total 1 results
Start Over Author "Zhu, Shou‐Fei" Topic chemical bonds Journal chemical communications
1 results on '"Zhu, Shou‐Fei"'

1. Copper-catalyzed enantioselective carbenoid insertion into S–H bonds.

Author

Zhang, Yong-Zhen, Zhu, Shou-Fei, Cai, Yan, Mao, Hong-Xiang, and Zhou, Qi-Lin

Subjects
*COPPER catalysts, *CARBENES, *CHEMICAL bonds, *ASYMMETRY (Chemistry), *CHIRALITY, *ESTERS, *COMPLEX compounds
Abstract

An asymmetric carbenoid insertion into S–H bonds catalyzed by copper–chiral spiro bisoxazoline complexes has been developed, in which a series of α-mercaptoesters were produced in high yields with moderate to good enantioselectivities (up to 85% ee); this result represents the best enantioselectivity in the catalytic asymmetric carbenoid S–H bond insertion reaction. [ABSTRACT FROM AUTHOR]

Published
2009
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