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1. A consecutive process for C–C and C–N bond formation with high enantio-and diastereo-control: direct reductive amination of chiral ketones using hydrogenation catalysts.

Author

Gilbert, Sophie H., Viseur, Virginie, and Clarke, Matthew L.

Subjects
AMINATION, KETONES, HYDROGENATION, CATALYSTS, CATALYSIS, TERTIARY amines
Abstract

High diastereoselectivity was observed in the Rh-catalysed reductive amination of 3-arylcyclohexanones to form tertiary amines. This was incorporated into a one-pot enantioselective conjugate addition and diastereoselective reductive amination, including an example of assisted tandem catalysis. [ABSTRACT FROM AUTHOR]

Published
2019
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