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Start Over Author "Kuan-Miao Liu" Journal chem. commun.
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1. Intermolecularradicaladdition reactions of α-iodo cycloalkenones and a synthetic study of the formal synthesis of enantiopurefawcettimine

Author

Kuan-Miao Liu, Chi-Min Chau, and Chin-Kang Sha

Subjects
Addition reaction, Indoles, Alkylation, Free Radicals, Molecular Structure, Scope (project management), Chemistry, Radical, Intermolecular force, Metals and Alloys, Cycloparaffins, Electrons, Stereoisomerism, General Chemistry, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Formal synthesis, Alkaloids, Materials Chemistry, Ceramics and Composites, Organic chemistry
Abstract

The generation of alpha-carbonyl vinyl radicals from alpha-iodo cycloalkenones, the scope of their participation in intermolecular addition reactions with electron-withdrawing olefins are studied and a synthetic study of the formal synthesis of enantiopure fawcettimine using this reaction is described.

Published
2008
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