1. Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate
- Author
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Charles T. O'Hara, Sophie H. Dale, Robert E. Mulvey, Gordon W. Honeyman, Alan R. Kennedy, David R. Armstrong, William Clegg, Eva Hevia, Ross W. Harrington, and Joaquín García-Álvarez
- Subjects
chemistry.chemical_classification ,Base (chemistry) ,Transamination ,Sodium ,Metals and Alloys ,chemistry.chemical_element ,Diisopropylamine ,General Chemistry ,Crystal structure ,Medicinal chemistry ,Catalysis ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,chemistry ,Materials Chemistry ,Ceramics and Composites ,Organic chemistry ,Reactivity (chemistry) ,Directed ortho metalation ,Zincate - Abstract
In a new type of reactivity for sodium TMP-zincate [(TMEDA)NaZn((t)Bu)(2)(TMP)] (1), transamination reactions with the amines diisopropylamine, DA(H), hexamethyldisilazane, HMDS(H) and chiral (R)-N-benzyl-alpha-methylbenzylamine have produced new sodium amido-di-tert-butyl zincates (all structurally characterised) with concomitant loss of TMP(H).
- Published
- 2008
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