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The slow dissolution process of zirconium oxide (ZrO 2) limits the efficient and energy-saving production of zirconium-rich basalt fibers with excellent alkali resistance for fiber-reinforced concrete. Therefore, it is necessary to investigate the optimum homogenization conditions to produce high-performance zirconium-rich basalt fibers. In this study, quenched zirconium-rich glasses and zirconium-rich fibers with the addition of 7 wt% ZrO 2 at different homogenization temperatures and time were prepared. The quenched melt structure was characterized by XRD and FTIR, and followed information about the melt structure obtained by Gaussian curve fitting of the FTIR spectra. The results indicated that obvious ZrO 2 crystals appeared in the melts and fibers with homogenization temperature below 1500 °C and time below 4 h. The degree of polymerization of zirconium-rich basalt melt was found to increase with increasing homogenization temperature and time. Meanwhile, the tensile strength and production stability of zirconium-rich fibers increased with increasing the degree of polymerization. The optimum homogenization temperature and time for zirconium-rich basalt fibers were concluded to be 1580 °C and 10 h, and the corresponding tensile strength is 1799 MPa and 1761 MPa, respectively. By diffusion experiment of ZrO 2 in basalt melt with altered major component content, it was found that the Ca, Mg, Na, and Fe significantly facilitated the melting of ZrO 2 into basalt melt by XRD and EDS. It was mainly attributed to the charge-compensating effect of metal cations on the [ZrO 6 ] octahedra, which promoted the homogenization of ZrO 2 in basalt melt. [ABSTRACT FROM AUTHOR]