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With the continuous development of electronic devices, miniaturization and high capacitance have become important factors in the fabrication of multilayer ceramic capacitors (MLCCs) with a Ni internal electrode (Ni-MLCCs). The typical thickness of the dielectric layer of commercial MLCCs is less than 1 μm, which implies a higher capacitance compared to MLCCs with a thicker dielectric layer. In this study, 1210-type Ni-MLCCs were prepared via a tape casting method using a BaTiO 3 powder chemically coated with Dy and Ho additives. The high capacitance (390 nF) Ni-MLCC sintered at 1220 °C exhibited a low dielectric loss (tan δ < 2%), high insulation resistance (>9000 MΩ), and temperature stability comparable to that of the EIA X5R standard (capacitance-temperature coefficient (TCC) = ΔC/C 25 °C ≤ ±15%, between -55–85 °C). Relaxation behavior was observed between 1 Hz and 10 kHz, following the modified Curie–Weiss law and the Vogel–Fulcher relationship. The capacitive temperature stability of Ni-MLCC is closely related to the applied direct current (DC) bias field. The EIA X7R stability (TCC ≤ ±15%, between -55–125 °C) of the Ni-MLCCs at 1220 °C was gained under dc-bias field 3 and 5 V/μm. The capacitance varied as alternating current (AC) electric fields were applied. The grain shell was sensitive to both the DC bias and AC fields, but the grain core was more sensitive to the DC bias electrical field than the AC field. Furthermore, the ferroelectric response in MLCC decreases with rising temperature. [ABSTRACT FROM AUTHOR]

Abstract Currently, there is an urgent need of extraordinary comprehensive pyroelectric materials for the wide application in detectors and energy harvesters. In this study, the (Pb 1–1.5 x La x)(Zr 0.86 Ti 0.14)O 3 (abbreviated as PLZT, x = 0.02, 0.03, 0.04 and 0.05) ceramics located in ferroelectric-antiferroelectric (FE-AFE) phase boundary were designed and synthesized by using conventional solid-state reaction method. The microstructures, phase structures, dielectric, ferroelectric, thermal depolarization and pyroelectric properties of the PLZT ceramics with different La content were investigated thoroughly. The XRD results show that the PLZT ceramics change from FE phase to AFE phase with increasing La content. The significant improvement of pyroelectric coefficient p and figures of merit (FOMs) are achieved in the PLZT ceramics with the increase in La content because of the increased metastable ferroelectric phase under the application of electric field. The (Pb 0.955 La 0.03)(Zr 0.86 Ti 0.14)O 3 (x = 0.03) ceramic exhibits not only high p of 5.2 × 10 − 8 C / cm 2 K and high depolarization temperature (T d) of 179 ℃ but also excellent FOMs with F i = 2.2 × 10 − 10 m / V , F v = 5.0 × 10 − 2 m 2 / C , and F d = 3.47 × 10 − 5 Pa − 1 / 2 . In addition, the highest p of 6.8 × 10 − 8 C / cm 2 K is achieved in (Pb 0.94 La 0.04)(Zr 0.86 Ti 0.14)O 3 (x = 0.04) ceramic. These results demonstrate that the PLZT ceramics of x = 0.03 and 0.04 are promising candidates for pyroelectric applications. [ABSTRACT FROM AUTHOR]

Reversible domain switching in aged acceptor-doped ferroelectric ceramics is a powerful method to achieve electrostrain due to the exchange of nonequal crystalline axes of domains. Nevertheless, previous work suggested that the strain obtained via reversible domain switching in unpoled ceramics was much lower than theoretical value. In this paper, we demonstrate that the strain in poled and aged acceptor-doped ferroelectric ceramics can be significantly enhanced when the driving electric field is perpendicular to the poling direction, originating from the exchange of nonequel crystalline axes of more domains. Consequently, the electrostrain of poled and aged 0.1 wt% MnO 2 -doped 0.05Pb(Mn 1/3 Sb 2/3 )O 3 −0.50PbZrO 3 −0.45PbTiO 3 could reach 0.225% which was 4.17 times larger than that of unpoled sample under a low electric field of 15 kV cm −1 . Moreover, the corresponding normalized strain d 33 * reached 1500 pm V −1 which significantly exceeded the values reported in ferroelectric ceramics. Our work provide a general effective method to enhance the electrostrain behavior via reversible domain switching in aged acceptor-doped ferroelectric ceramics. [ABSTRACT FROM AUTHOR]