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In this study, the effects of different silicon carbide (SiC) particle sizes on the viscosity and curing behavior of alumina (Al 2 O 3) ceramic suspensions were thoroughly investigated. The findings revealed that increasing the size of SiC particles led to a noticeable decrease in the viscosity of the suspension. The Al 2 O 3 ceramic suspension with 0.6 μm SiC powder demonstrated a shallower cure depth and wider excess width compared to the suspension with 1.0 μm SiC powder. Sintering tests demonstrated that the properties of the SiC–Al 2 O 3 ceramics improved at higher sintering temperatures. Moreover, a high-performance honeycomb ceramic was successfully designed and fabricated with a porosity and compressive strength of 30.8 % and 188 MPa, respectively. Finally, the SiC–Al 2 O 3 honeycomb ceramics were effectively applied in heat insulation and oil-water separation applications, demonstrating their remarkable capabilities. [ABSTRACT FROM AUTHOR]

The excellent recyclability of SiC foam renders it an ideal catalyst in the field of photocatalytic degradation, however to further improve its photocatalytic efficiency remains a major challenge in current research. In this regard, a honeycomb-like porous SiC foam was successfully constructed through freeze-drying and polymer-to-ceramic derivation method, with two-dimensional Ti 3 C 2 T x nanosheets anchored on its three-dimensional framework. Their photocatalytic performances were evaluated by the degradation of methylene blue (MB) under visible-light irradiation. All Ti 3 C 2 T x /SiC hybrid foams show superior photocatalytic degradation capability compared with SiC foam, with a highest removal rate (adsorption and degradation) reaching 94.4% for TSF-4, denoting an increasement of 50.4%. Even after five cycles, the removal rate remained at 91.4% with only a slightly loss of 3%, suggesting its excellent recycling performance. These desirable results stem from the unique structural design, in which the porous structure facilitates the contact between catalyst and pollutant, while the Ti 3 C 2 T x /SiC heterojunction promotes effective separation of photogenerated carriers. This work paves the way for the development of lightweight, efficient and easily recyclable photocatalyst for wastewater purification. [ABSTRACT FROM AUTHOR]

Silicon oxycarbide (SiOC) ceramics have been used to fabricate microwave-absorbing metastructures, demonstrating impressive absorption capabilities. However, SiOC ceramic metastructures with excellent performance require simple fabrication processes and appropriate mechanical and electromagnetic properties. In this study, a solvent-free photosensitive polysiloxane preceramic was developed by blending methoxy/hydroxy polysiloxanes with acrylates, with a ceramic yield of over 60% after curing using a novel two-step ultraviolet (UV)/thermal method. The composition and microstructure of SiOC ceramics can be designed by controlling the preceramic composition. Dense, crack-free gyroid-shellular shaped triple periodic minimal surface (GS-TPMS) electromagnetic metastructures were fabricated using digital light processing (DLP) 3D printing technology. By designing the porosity of the GS-TPMS structure to 51%, an effective absorption bandwidth that covers the X-band can be achieved at a thickness of 3.1 mm. The honeycomb structure, with a geometric density of 0.69 g/cm3, exhibited a high compressive strength of 107.05 MPa. This paper presents an efficient approach for the prompt and customized fabrication of lightweight ceramic metastructures with outstanding microwave absorption properties. • A solvent-free polysiloxane/acrylate hybrid preceramics is developed for 3D printing. • The UV/thermal two-stage treatment achieved cross-linking curing of the preceramics. • Multiscale design of SiOC ceramics for enhanced microwave absorption properties. • SiOC ceramic metastructures with effective absorption in the X-band are prepared. [ABSTRACT FROM AUTHOR]

Due to the limitations of the Kramers-Kronig relationship, how to achieve ultra-wide effective absorption bandwidth remains a challenge for typical magnetic-dielectric absorbers. In the present work, we have explored the possibility of obtaining ultra-wide absorption bandwidth in FeSiAl composites with help of efficient electromagnetic (EM) simulation software-Computer Simulation Technology (CST). Flaky FeSiAl powders covered by CeO 2 have been prepared, in which EM parameters can be tuned by filling ratio of FeSiAl/CeO 2 in FeSiAl/CeO 2 -paraffin composites. The filling ratio has an effect on impedance matching and EM parameters by the arrangement of particles in the paraffin. The composite with 30 wt% flaky FeSiAl/CeO 2 achieves an effective absorption bandwidth (EAB) of 6.48 GHz and the optimal microwave absorption efficiency of 1499.3 dB GHz/(wt%⋅m) at 1.9 mm. Integrated with a macroscale honeycomb structural design, the FeSiAl/CeO 2 composites based metastructure exhibits broadband microwave absorption with an EAB of 14.224 GHz covering from 3.776 GHz to 18 GHz and reflection loss of-65.61 dB at 8.5 GHz. The excellent performances of the designed absorber are ascribed to multiple loss by integrating EM parameters of flaky FeSiAl/CeO 2 and the geometry parameters of honeycomb metasrtucture. The present work makes flaky FeSiAl/CeO 2 composites possible to achieve broadband microwave absorption. [ABSTRACT FROM AUTHOR]

Peculiarities of sintering of foamy ceramic filters based on submicron aluminum oxide powders with additions of titanium oxide and manganese dioxide nanopowders are considered. The processes of removal of polymeric and binder paraffin material during sintering have been studied. The physical and mechanical properties of the obtained porous permeable filters with a foamy structure were analyzed in details. At a sintering temperature in an air atmosphere of 1350 °C, sufficiently high physical and mechanical properties were obtained, which made it possible to use the developed filters as catalyst carriers for vehicle exhaust gases. Bench comparative tests have shown that ceramic filters with a foamed structure are promising catalysts for afterburning car exhaust gases instead of ceramic honeycomb blocks of catalyst carriers. The developed technology allows reducing the sintering temperature of porous foam ceramic filters to 1350 °C and replacing expensive high-temperature ceramic heaters with cheaper nickel-chromium ones. [ABSTRACT FROM AUTHOR]

A significant challenge in electrolyte-supported solid oxide fuel cells (SOFCs) pertains to the substantial thickness of the electrolyte, resulting in elevated operational temperatures that hinder commercial viability. In this research, we utilized digital light processing (DLP) 3D printing technology to fabricate ultra-thin honeycomb electrolyte-supported SOFCs and subsequently evaluated their performance. Through the use of ultraviolet absorbers, we achieved a shallow curing depth (60.3 μm), which facilitated the creation of ultra-thin electrolyte samples. We investigated the mechanical properties of electrolytes with various honeycomb structures, finding that the square honeycomb structure exhibited the highest mechanical integrity, with an average failure load of 1.01 N. Finally, we assessed the electrochemical performance, observing a substantial power density of 215.4 mW/cm2, representing a twofold increase compared to the 114 mW/cm2 achieved by the same method in a flat primary cell. [ABSTRACT FROM AUTHOR]

Porous honeycomb mullite ceramics were controllably fabricated in-situ using stereolithography 3D printing. The effects of the dispersant type and content on the rheological behavior of the mullite precursor slurry were investigated. Additionally, the influence of the debinding atmosphere (air and argon) on the quality of the samples and formation of cracks was also studied. The results indicated that oleic acid (OA), 3-glycidoxypropylthrimethoxysilane (KH560), and disperbyk (BYK111) displayed the capability to create low-viscosity and highly stable slurries. Among these KH560 was proved to be the most effective. The mullite precursor slurry containing 4 wt% KH560 dispersants exhibited a shear thinning behavior. It displayed a viscosity of 0.26 Pa·s at a shear rate of 30 s−1. The mullite ceramic parts displayed good a dimensional resolution at an exposure dose of 5.47 mJ/cm2. During the debinding process, the printed parts were susceptible to cracking and deformation in air, but remained devoid of defects in argon. When the samples were sintered at 1600 °C, the corundum phase transformed almost completely into the mullite phase. The linear shrinkage values were 5.81%, 6.33%, and 10.26% in the O-X, O–Y and O-Z directions, respectively. [ABSTRACT FROM AUTHOR]

In this study, Al 2 O 3 honeycomb sandwich structures with different core geometries (square, triangular, circular) have been fabricated through an additive manufacturing system based on the stereolithography (SLA) method. The debinding procedure was performed under both nitrogen and air atmospheres. The impacts of the debinding atmosphere and core geometry on the densification and mechanical properties were investigated. The stiffness and flexural strength of the ceramics were examined experimentally using an impulse excitation of vibration technique and a three-point bending test, respectively. The specific stiffness and specific strength of the ceramics were also evaluated, with the core geometries taken into consideration. The outcomes showed that higher densification was achieved when the ceramics were exposed to debinding in nitrogen. The stiffness values were found to be similar for the same debinding condition within the honeycomb sandwich structures, irrespective of the core geometry. Notably, the highest specific stiffness (98 MNm/kg) was achieved for the samples subjected to debinding in nitrogen with a square core geometry. Furthermore, ceramics with square cores for debinding in a nitrogen atmosphere also demonstrated the highest performance in terms of specific strength (110 kNm/kg) within the honeycomb structures. This study demonstrated that Al 2 O 3 honeycomb sandwich structures with square cores may be suitable candidates for lightweight-structure demanding applications. [ABSTRACT FROM AUTHOR]