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Silicon oxycarbide (SiOC) ceramics have been used to fabricate microwave-absorbing metastructures, demonstrating impressive absorption capabilities. However, SiOC ceramic metastructures with excellent performance require simple fabrication processes and appropriate mechanical and electromagnetic properties. In this study, a solvent-free photosensitive polysiloxane preceramic was developed by blending methoxy/hydroxy polysiloxanes with acrylates, with a ceramic yield of over 60% after curing using a novel two-step ultraviolet (UV)/thermal method. The composition and microstructure of SiOC ceramics can be designed by controlling the preceramic composition. Dense, crack-free gyroid-shellular shaped triple periodic minimal surface (GS-TPMS) electromagnetic metastructures were fabricated using digital light processing (DLP) 3D printing technology. By designing the porosity of the GS-TPMS structure to 51%, an effective absorption bandwidth that covers the X-band can be achieved at a thickness of 3.1 mm. The honeycomb structure, with a geometric density of 0.69 g/cm3, exhibited a high compressive strength of 107.05 MPa. This paper presents an efficient approach for the prompt and customized fabrication of lightweight ceramic metastructures with outstanding microwave absorption properties. • A solvent-free polysiloxane/acrylate hybrid preceramics is developed for 3D printing. • The UV/thermal two-stage treatment achieved cross-linking curing of the preceramics. • Multiscale design of SiOC ceramics for enhanced microwave absorption properties. • SiOC ceramic metastructures with effective absorption in the X-band are prepared. [ABSTRACT FROM AUTHOR]

Due to the limitations of the Kramers-Kronig relationship, how to achieve ultra-wide effective absorption bandwidth remains a challenge for typical magnetic-dielectric absorbers. In the present work, we have explored the possibility of obtaining ultra-wide absorption bandwidth in FeSiAl composites with help of efficient electromagnetic (EM) simulation software-Computer Simulation Technology (CST). Flaky FeSiAl powders covered by CeO 2 have been prepared, in which EM parameters can be tuned by filling ratio of FeSiAl/CeO 2 in FeSiAl/CeO 2 -paraffin composites. The filling ratio has an effect on impedance matching and EM parameters by the arrangement of particles in the paraffin. The composite with 30 wt% flaky FeSiAl/CeO 2 achieves an effective absorption bandwidth (EAB) of 6.48 GHz and the optimal microwave absorption efficiency of 1499.3 dB GHz/(wt%⋅m) at 1.9 mm. Integrated with a macroscale honeycomb structural design, the FeSiAl/CeO 2 composites based metastructure exhibits broadband microwave absorption with an EAB of 14.224 GHz covering from 3.776 GHz to 18 GHz and reflection loss of-65.61 dB at 8.5 GHz. The excellent performances of the designed absorber are ascribed to multiple loss by integrating EM parameters of flaky FeSiAl/CeO 2 and the geometry parameters of honeycomb metasrtucture. The present work makes flaky FeSiAl/CeO 2 composites possible to achieve broadband microwave absorption. [ABSTRACT FROM AUTHOR]

Microwave absorbing (MA) materials with yolk-shell structures have been extensively studied in impedance matching. However, the impedance matching achieved by the complementary effect of the core and the shell does not determine the reflection of the microwaves upon the occurrence at the first incidence. The interaction between the outer layer of materials and the electromagnetic waves significantly impacts the MA properties of materials. In this study, the impedance matching improvement method of the shell structure was further explored by preparing CoFe 2 O 4 @HCN (honeycomb carbon with N-doping) through the hydrothermal method followed by hydrolysis, polymerization, etching, and annealing. The resulting structure with heteroatoms doping provided the novel CoFe 2 O 4 @HCN with excellent impedance matching and multiple loss mechanisms contributing to MA process. The absorber with a filler loading of 40% exhibited an RL min of −68.03 dB with a matching thickness of 2.5 mm. The efficient absorbing bandwidth reached 5.92 GHz (a change from 11.92 to 17.84 GHz) at 1.99 mm thickness. Interestingly, these findings look promising for future synthesis and application of yolk-shell structure microwave absorbers. [ABSTRACT FROM AUTHOR]