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In this study, novel porous LaPO 4 ceramics possessing closed spherical pores and thin pore walls have been firstly synthesized using the particle-stabilized foaming method. Affected by the calcination temperature together with solid loading, the obtained porous LaPO 4 ceramics exhibit high porosity (81.69–94.21 %), very low thermal conductivity (κ) (0.124–0.398 W m−1 K−1) and relatively high compressive strength (0.886–9.30 MPa). When the calcination temperature and solid loading are 1500 °C and 35 wt%, optimized porous LaPO 4 ceramics achieve a better balance between thermal conductivity (0.160 W m−1 K−1) and compressive strength (2.07 MPa). Based on this, the prediction model for the thermal conductivity is screened and the thermal insulating capability is further verified. This work suggests that porous LaPO 4 ceramics have the potential to be applied as thermal insulation material in the future. [ABSTRACT FROM AUTHOR]