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Hinai green tuff, which is found in Akita Prefecture, Japan, is used for the production of building materials, etc. About 60% of all stone is emitted as waste powder and therefore it is important to find ways for recycling it. In this work, the characteristics of green tuff powder have been investigated. The results of scanning electron microscope (SEM) and elemental map observations indicate that the green tuff contains TiO2 on zeolite. The green tuff can therefore be used as a natural catalyst for producing hydrogen peroxide with moisture and oxygen with light. The optimum calcined temperature of the green tuff powder is about 800 °C, producing the hydroxyl radical from hydrogen peroxide decomposition without ultraviolet light (UV) and decomposition of the superoxide anion. As the application of green tuff powder, Cavendish banana trees found in the Philippines infected by a new Panama disease were treated with powder suspension in order to remove the fungus (a type of Fusarium wilt) due to the photocatalyst characteristics of powder. The suspension, prepared by using the powder was sprayed on the infected banana trees for about one month. Photograph observation indicated that the so-called 800 °C suspension spray was more effective in growing the infected banana trees. [ABSTRACT FROM AUTHOR]

Techniques to control vehicle engine emissions have been under increasing need for development during the last few years in the more and more strictly regulated society. In this study, vehicle-aged heavy-duty catalysts from diesel and natural gas engines were analyzed using a cross-sectional electron microscopy method with both a scanning electron microscope and a transmission electron microscope. Also, additional supporting characterization methods including X-ray diffractometry, X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy and catalytic performance analyses were used to reveal the ageing effects. Structural and elemental investigations were performed on these samples, and the effect of real-life ageing of the catalyst was studied in comparison with fresh catalyst samples. In the real-life use of two different catalysts, the poison penetration varied greatly depending on the engine and fuel at hand: the diesel oxidation catalyst appeared to suffer more thorough changes than the natural gas catalyst, which was affected only in the inlet part of the catalyst. The most common poison, sulphur, in the diesel oxidation catalyst was connected to cerium-rich areas. On the other hand, the severities of the ageing effects were more pronounced in the natural gas catalyst, with heavy structural changes in the washcoat and high concentrations of poisons, mainly zinc, phosphorus and silicon, on the surface of the inlet part. [ABSTRACT FROM AUTHOR]