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2 results on '"Zhongzhou Yi"'

1. Selective Oxidation of Cyclohexane to Cyclohexanone Catalyzed by Phenanthroline–CuCl2 Complex

Author

Jucheng Zhang, Zhongzhou Yi, Wei Liu, Mingzhu Wu, and Ying Li

Subjects
Cyclohexane, Phenanthroline, Inorganic chemistry, chemistry.chemical_element, Cyclohexanone, General Chemistry, Copper, Catalysis, chemistry.chemical_compound, chemistry, Polymer chemistry, Copper chloride, Selectivity, Organometallic chemistry
Abstract

A highly efficient oxidation of cyclohexane to cyclohexanone is accomplished over phenanthroline–CuCl2 catalyst in relatively mild conditions. This study realized nearly 100% selectivity for cyclohexanone at 24.4% conversion of cyclohexane. The reaction has been studied by various parameters like performance of copper(II) salts, effect of solvents, influence of bases, the ratio of o-phenanthroline: CuCl2, and reaction time. In order to further study this reaction system, the possible mechanism was proposed.

Published
2008

2. Selective Oxidation of Cyclohexane to Cyclohexanone Catalyzed by Phenanthroline–CuCl2 Complex.

Author

Ying Li, Mingzhu Wu, Wei Liu, Zhongzhou Yi, and Jucheng Zhang

Subjects
OXIDATION, CYCLOHEXANE, COPPER, PEROXIDATION, ALICYCLIC compounds
Abstract

A highly efficient oxidation of cyclohexane to cyclohexanone is accomplished over phenanthroline–CuCl2 catalyst in relatively mild conditions. This study realized nearly 100% selectivity for cyclohexanone at 24.4% conversion of cyclohexane. The reaction has been studied by various parameters like performance of copper(II) salts, effect of solvents, influence of bases, the ratio of o-phenanthroline: CuCl2, and reaction time. In order to further study this reaction system, the possible mechanism was proposed. [ABSTRACT FROM AUTHOR]

Published
2008
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