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1. The Mechanism of N2O Decomposition on Fe-ZSM-5: An Isotope Labeling Study.

Author

Pirngruber, Gerhard D. and Roy, Pijus K.

Subjects
*NITROGEN, *IRON, *CHEMICAL reactions, *CLUSTER theory (Nuclear physics), *METALS, *NATIVE element minerals
Abstract

The mechanism of N2O decomposition over an 18O-labeled Fe-ZSM-5 catalyst was studied. The isotope distribution of the O2 produced during N2O decomposition was statistical. This shows that O2 was formed from a pool of equilibrated surface oxygen atoms. The size of the pool was 1.0 O/Fe, i.e. most or all of the iron clusters took part in the reaction. The reactivity of the oxygen atoms in the pool was low. They did not exchange with 18O2 to a significant extent. [ABSTRACT FROM AUTHOR]

Published
2004
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