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2. Vanillin Hydrodeoxygenation: Kinetic Modelling and Solvent Effect

Author

Sulman, Alexandrina, primary, Mäki-Arvela, Päivi, additional, Bomont, Louis, additional, Fedorov, Vyacheslav, additional, Alda-Onggar, Moldir, additional, Smeds, Annika, additional, Hemming, Jarl, additional, Russo, Vincenzo, additional, Wärnå, Johan, additional, Käldström, Mats, additional, and Murzin, Dmitry Yu., additional

Published
2018
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3. Vanillin Hydrodeoxygenation: Kinetic Modelling and Solvent Effect

Author

Vincenzo Russo, Annika Smeds, Mats Käldström, Louis Bomont, Alexandrina Sulman, Jarl Hemming, Vyacheslav Fedorov, Dmitry Yu. Murzin, Johan Wärnå, Päivi Mäki-Arvela, Moldir Alda-Onggar, Sulman, Alexandrina, Mäki-Arvela, Päivi, Bomont, Loui, Fedorov, Vyacheslav, Alda-Onggar, Moldir, Smeds, Annika, Hemming, Jarl, Russo, Vincenzo, Wärnå, Johan, Käldström, Mat, and Murzin, Dmitry Yu.

Subjects
Vanillin, Hydrodeoxygenation, Chemistry (all), 02 engineering and technology, General Chemistry, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, Catalysis, Catalysi, 0104 chemical sciences, Solvent, chemistry.chemical_compound, Kinetic modelling, chemistry, Organic chemistry, Guaiacol, Solvent effects, 0210 nano-technology, Selectivity, Tetrahydrofuran
Abstract

Vanillin hydrodeoxygenation was investigated using Pt/C catalyst in the temperature and total pressure ranges of 80–200 °C and 20–30 bar in several solvents, such as tetrahydrofuran, 2-propanol, water and in solventless conditions using 1:1 mass ratio of vanillin to guaiacol. The results revealed that the rate increased with increasing solvent polarity as follows: tetrahydrofuran

Published
2018

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