1. Mechanochemically modified aluminosilicates for efficient oxidation of vanillyl alcohol
- Author
-
Esmail Doustkhah, Daily Rodríguez-Padrón, Hamid Reza Shaterian, Somayeh Ostovar, Rafael Luque, Farveh Saberi, and Ana Franco
- Subjects
Process Chemistry and Technology ,Vanillin ,Prepared Material ,General Chemistry ,Catalysis ,Vanillyl alcohol ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Aluminosilicate ,Surface modification ,Selectivity ,Iron oxide nanoparticles - Abstract
A mechanochemical protocol was applied to the synthesis of a magnetic material based on iron oxide nanoparticles and Al-SBA-15. Full characterization of the prepared Fe2O3/Al-SBA-15 evidenced the effective functionalization of the aluminosilicate surface. Particularly, TEM analysis revealed that the mechanochemical protocol did not considerable affect the hexagonal ordered structure of Al-SBA-15. DRIFT experiments of Fe2O3/Al-SBA-15 showed interesting acidic properties, which can be further associated to a good catalytic performance. The catalytic behavior of the prepared material was tested in the oxidation of vanillyl alcohol to vanillin, displaying an excellent activity and selectivity. The material resulted to be highly stable in the aforementioned reaction, without considerable decrease of conversion after 10 reuse cycles.
- Published
- 2019
- Full Text
- View/download PDF