1. Diffusion of oxygen through a pulp and paper residue barrier
- Author
-
Guy Lefebvre, Alexandre R. Cabral, Isabelle Racine, and Fabien Burnotte
- Subjects
Waste management ,Pulp (paper) ,chemistry.chemical_element ,engineering.material ,Geotechnical Engineering and Engineering Geology ,Acid mine drainage ,Deinking ,Pulp and paper industry ,Oxygen ,Tailings ,law.invention ,Residue (chemistry) ,chemistry ,Oxygen barrier ,law ,Soil water ,engineering ,Geotechnical engineering ,Civil and Structural Engineering - Abstract
Acid mine drainage can be curbed or reduced significantly by covering tailings sites with an oxygen barrier. In this study, the ability of pulp and paper residues, more specifically deinking residues, to function as such a barrier was investigated. Field data from two sites show that O2 diffusion through the barriers can be greatly reduced. To better understand how oxygen migrates through deinking residues and to develop prediction tools for future design with deinking residues, one-dimensional effective diffusion coefficients (De) were determined by fitting laboratory experimental curves (O2 concentration versus time data) to curves obtained from computer simulations. The results obtained confirmed the behaviour observed in soil covers: the effective diffusion coefficients are highly dependent on the degree of saturation (Sr) of the compacted material. The De values obtained in this study compare well with those published in the literature for several materials compacted at similar Sr. The De values varied from 8.3 × 10-9 m2/s (Sr approximately 91%) to 9.7 × 10-7 m2/s (Sr approximately 76%). The O2 consumption by biodegradation appears to be an important factor in the reduction of the O2 flux that can reach the bottom of the barrier.Key words: oxygen diffusion, pulp and paper residues, barrier, acid mine drainage.
- Published
- 2000