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Modernization and industrialization have significantly increased energy consumption, causing environmental problems. Given that China is the largest energy user, the rise in building energy consumption necessitates clean energy alternatives. The purpose of this study is to summarize typical building models for primary and secondary schools in Hainan Province, and to use software to simulate and calculate the photovoltaic utilization potential of primary and secondary school buildings. In China, the government is usually the manager of primary and secondary schools, and due to their architectural characteristics, these buildings can be used to assess photovoltaic applications. The aim is to drive the application of photovoltaic systems in all types of buildings and promote urban energy reform. This study summarizes the types of primary and secondary school buildings in Hainan Province and analyzes them. It evaluates rooftop photovoltaic projects at the Second Middle School and the Siyuan School in Wanning City, Hainan Province, and uses PVsyst 7.2 software to assess the photovoltaic utilization potential. The results show that the optimal orientation in Hainan Province is south-facing, and the optimal inclination angle is 10° to 20°. The most favorable orientations of facade photovoltaic systems are 20° southeast or southwest. The longest dynamic investment payback period is approximately 15 years, and the environmental benefits are $0.012/kWh. The findings indicate significant potential for photovoltaic applications in primary and secondary school buildings. A combination of facade and rooftop photovoltaics can result in the zero-energy consumption of these buildings, reducing the pressure on urban power grids and achieving sustainable utilization.