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[Display omitted] • Characterization of PoChi reveals its efficacy in chitin degradation. • PoChi exhibits significant metal ion stability and high enzymatic activity. • Fusion enzymes demonstrate enhanced insoluble chitin degradation. • PoChi-FnIII-ChBD shows the highest activity among reported chitinases. N-acetyl-D-glucosamine and its dimer are degradation products of chitin waste with great potential in therapeutic and agricultural applications. However, the hydrolysis of insoluble chitin by chitinases remains a major bottleneck. This study investigated the biochemical properties and catalytic mechanisms of PoChi chitinase obtained from Penicillium oxalicum with a focus on enhancing its efficiency during the degradation of insoluble chitin. Recombinant plasmids were engineered to incorporate chitin-binding (ChBD) and/or fibronectin III (FnIII) domains. Notably, PoChi-FnIII-ChBD exhibited the highest substrate affinity (K m = 2.7 mg/mL) and a specific activity of 15.4 U/mg, which surpasses those of previously reported chitinases. These findings highlight the potential of engineered chitinases in advancing industrial biotechnology applications and offer a promising approach to more sustainable chitin waste management. [ABSTRACT FROM AUTHOR]

[Display omitted] • Fenton reagent significantly reduced ARGs and MGEs abundance. • Addition of Fenton reagent restricted the late-phase resurgence of ARGs. • MGEs were responsible for variations in the ARG profiles in C treatment. • Acinetobacter, Corynebacterium, and Clostridium_sensu_stricto_1 were the key hosts of ARGs. Livestock manure harbors antibiotic resistance genes (ARGs), and aerobic composting (AC) is widely adopted for waste management. However, mitigating ARG resurgence in later stages remains challenging. This work aims to curb ARGs rebounding through a Fenton-like reaction during food waste and swine manure co-composting. Results revealed that 0.025 % zerovalent iron (ZVI) + 0.5 % hydrogen peroxide (H 2 O 2) facilitated maximum ARG, mobile genetic elements (MGEs), and 16 s rRNA removal with reductions of 2.68, 2.69, and 1.4 logs. Spectroscopic analysis confirmed Fenton-like reaction and cell apoptosis analysis indicated that 0.025 % ZVI and 0.5 % H 2 O 2 treatment had the maximum early apoptosis, least observed, and normal cells on day 30. Redundancy analysis highlighted the influence of bacterial communities and physicochemical properties on ARGs, with MGEs playing a crucial role in Fenton treatments. Our findings suggest incorporating ZVI and H 2 O 2 in composting can significantly reduce ARGs and enhance waste management practices. [ABSTRACT FROM AUTHOR]

[Display omitted] • New study to expand the use of sugarcane bagasse (SCB) in the biorefinery concept. • Minimized cellulase at 15 U/g NaOH-pretreated SCB efficiently released sugars (70.8%). • K. oxytoca KIS004-91T produced D-lactate at 99.9 g/L with 0.97 g/g by fed-batch SSF. • D-lactate yield approached 97% theoretical maximum with 99.5% optical purity. Sugarcane bagasse (SCB) was utilized for efficiently producing optically pure D-(−)-lactate by Klebsiella oxytoca KIS004-91T strain. Cellulase (15 U/g NaOH-treated SCB) sufficiently liberated high sugars with saccharifications of 79.8 % cellulose and 52.5 % hemicellulose. For separated hydrolysis and fermentation, D-(−)-lactate was produced at 53.5 ± 2.1 g/L (0.98 ± 0.01 g/g sugar utilized or 0.71 ± 0.01 g/g total sugars) while D-(−)-lactate at 47.2 ± 1.8 g/L (0.78 ± 0.03 g/g sugar used or 0.69 ± 0.01 g/g total sugars) was obtained under simultaneous saccharification and fermentation (SSF). D-(−)-lactate at 99.9 ± 0.9 g/L (0.97 ± 0.01 g/g sugar utilized or 0.78 ± 0.01 g/g total sugars) was improved via fed-batch SSF. Based on mass balance, raw SCB of 7 kg is required to produce 1 kg D-(−)-lactate. Unlike others, D-(−)-lactate production was performed in low-cost salt medium without requirements of rich nutrients. Costs regarding medium, purification, and waste disposal may be reduced. This unlocks economic capability of SCB bioconversion or agricultural and agro-industrial wastes into high valuable D-(−)-lactate. [ABSTRACT FROM AUTHOR]

European regulations require that by 2030 waste suitable for recycling, material recovery, or energy recovery will no longer be allowed in landfills. MSW composition in non-recyclable containers affects what measures for recovery could be implemented. This study is a screening examination of 32 non-recyclable MSW samples in the Getafe municipality (Spain). In addition to non-combustible elements, MSW is separated into 15 waste materials. Merely 18.1 % of the non-recyclable component is placed in appropriate containers. Composition of all materials is analyzed. MSW samples are grouped into six clusters with similar properties using the K-nearest neighbor methodology. Representative sample from each cluster is pyrolyzed at 520 °C. The main product of pyrolysis is liquid, which makes up 57.9 wt%, while solid and gas fractions are 16.4 and 16.5 wt%, respectively. Liquid fraction is a blend of aromatic, aliphatic, oxygenated, and nitrogenated compounds, while gas fraction is mainly CO 2 ., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

China generates over 100 million tons of food waste annually, leading to significant environmental pollution and health risks if not managed properly. Converting FW into a high-value-added platform molecule, lactic acid (LA), through fermentation offers a promising approach for both waste treatment and resource recovery. This paper presents a comprehensive review of recent advancements in LA production from FW, focusing on pure strains fermentation and open fermentation technologies, metabolic mechanisms, and problems in fermentation. It also assesses purification methods, including molecular distillation, adsorption, membrane separation, precipitation, esterification and hydrolysis, solvent extraction, and in-situ separation, analyzing their efficiency, advantages, and disadvantages. However, current research encounters several challenges, including low LA yield, low optical purity of L-(+)-LA, and difficulties in the separation and purification of LA. The integration of in-situ separation technology coupled with multiple separation methods is highlighted as a promising direction for future advancements., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

[Display omitted] • Tomato waste enhances I. galbana cultivation efficiency for producing fucoxanthin. • Soluble lycopene and β-carotene upregulated genes expressions PSY , LCYB , and ZEP3. • Hydrolyzed tomato waste in growth medium enhances fucoxanthin synthesis. • Tomato waste as nutrient source sustainably yields valuable products in microalgae. Vegetable waste, rich in bioactive compounds, offers a promising resource for producing value-added products. This study explored the use of tomato waste, containing glucose (40 mg/g), lycopene (95.12 μg/g), and β-carotene (24.31 μg/g), for cultivating fucoxanthin-rich Isochrysis galbana. Water-soluble lycopene (2.0 μg/mL) and β-carotene (0.4 μg/mL) effectively upregulated key carotenoid synthesis genes and boosted cell growth and fucoxanthin production (3.64 and 3.60 pg/cell, respectively) within 10 days in a mixotrophic culture. Optimized tomato waste hydrolysate achieved a high cell density of 1.21 × 107 cells/mL, 2.13 g/L biomass, and 21.02 mg/g fucoxanthin. This study highlights the potential of combining tomato waste with microalgae for a novel and innovative approach towards waste management and resource utilization. [ABSTRACT FROM AUTHOR]

[Display omitted] • Urban food waste—green infrastructure nexus is feasible. • Food waste digestate significantly promoted green roof plant growth and functions. • Food waste digestate is better than digestate biochar in green roof promotion. • 20% performed better than 10% both in digestate and digestate biochar. Waste—Green Infrastructure Nexus is crucial to mitigate carbon emissions in waste disposal and promote eco-functions of green infrastructure in a circular bio-economy. Our purpose is to verify the feasibility of the nexus via "food waste anaerobic digestion — digestate/digestate biochar — green roof promotion". The results found that food waste digestate and digestate biochar significantly promoted green roof plant growth, evapotranspiration, rainwater retention, runoff reduction, and prevention of nutrient leaching. Digestate treatments were better than digestate biochar for the green roof promotion. The promotion ranked consistently with 20 % digestate > 10 % digestate > 20 % digestate biochar > 10 % digestate biochar > control in stolon growth, leaf emergence, branching of Paspalum vaginatum , green roof establishment, rainwater retention, runoff reduction, and the leaching of nitrogen, phosphorus, potassium. This study demonstrated that food waste could be regenerated to promote urban green infrastructure to form a circular bio-economy by the Waste—Green Infrastructure Nexus. [ABSTRACT FROM AUTHOR]

[Display omitted] • FNA pretreatment can significantly improve the solubilization of organic waste. • pH change within the system can adversely impact the FNA pretreatment performance. • Effective FNA concentration may decrease due to NO 2 – consumption by denitrifiers. • FNA-pretreated organic waste does not always show a higher biogas production in AD. • FNA at 1.0–5.2 mg FNA-N/L effectively controlled H 2 S-odor in the organic wastes. This work investigated the effectiveness of free nitrous acid (FNA) in enhancing organic waste solubilization to improve biogas production in anaerobic digestion (AD). The results indicated that FNA pretreatment can enhance soluble organic content and control H 2 S odor in tested organic wastes, including food waste, sewage sludge, and their combination. However, a significant decrease (>50 %) in FNA concentration was found in the reactors, possibly due to denitrifier-driven NO 2 – consumption. Biochemical methane potential (BMP) tests showed a 25 ± 8 % enhancement in CH 4 production in the reactors fed with mixed substrate pretreated with 2.9 mg FNA-N/L. However, the presence of NO 2 – (325.6–2368.0 mg N/L) in some BMP reactors, due to carryover from FNA pretreatment, adversely affected CH 4 production (>55 %) and prolonged lag time (>4.2 times). These findings are valuable for researchers and practitioners in waste management, offering insights for implementing FNA pretreatment to enhance the biodegradability of organic wastes in AD. [ABSTRACT FROM AUTHOR]

[Display omitted] • A novel ADED system was proposed to overcome ammonia inhibition in anaerobic digestion. • ADED technology effectively reduced the NH 4 +-N concentration to below 2,000 mg/L. • ADED achieves a remarkable 1.43-fold increase in methane production under 5,000 mg/L NH 4 +-N. • ADED technology alleviated methane production inhibition under 10,000 mg/L NH 4 +-N. • LCIA assessment reveals environmentally friendly ADED enables nutrient recovery, offering sustainable waste management. Ammonia inhibition is a common issue encountered in anaerobic digestion (AD) when treating nitrogen-rich substrates. This study proposed a novel approach, the electrodialysis-integrated AD (ADED) system, for in-situ recovery of ammonium (NH 4 +) while simultaneously enhancing AD performance. The ADED reactor was operated at two different NH 4 +-N concentrations (5,000 mg/L and 10,000 mg/L) to evaluate its performance against a conventional AD reactor. The results indicate that the ADED technology effectively reduced the NH 4 +-N concentration to below 2,000 mg/L, achieving this with a competitive energy consumption. Moreover, the ADED reactor demonstrated a 1.43-fold improvement in methane production when the influent NH 4 +-N was 5,000 mg/L, and it effectively prevented complete inhibition of methane production at the influent NH 4 +-N of 10,000 mg/L. The life cycle impact assessment reveals that ADED technology offers a more environmentally friendly alternative by recovering valuable fertilizer from the AD system. [ABSTRACT FROM AUTHOR]

The heterotrophic nitrification aerobic denitrification (HNAD) process can withstand the environment with high NH 4 + -N concentration and complex components, and has the potential to be an effective scheme for nitrogen removal of anaerobically treated leachate from municipal solid waste incineration plant. But its mechanism is still unclear and the NH 3 stripping process has received little attention. At the same time, the high concentration of NH 4 + -N in the anaerobically treated leachate also has great recycling potential. In this study, typical HNAD microorganisms were enriched and used for nitrogen removal from anaerobically treated leachate. A one-step system with a total nitrogen removal ratio of more than 98 % was constructed. Isotopic labeling experiments showed that nitrogen was not the main product. The important role of NH 3 stripping in the HNAD system was defined, and 46.63 % nitrogen was recovered on this basis., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

[Display omitted] • Microbial agent promoted the large-scale composting maturation at low temperatures. • The compost began by introducing microorganisms at a range of −10 ℃ to −3 ℃. • The compost reached a high temperature (55 ℃ to 70 ℃) for a duration of 14 weeks. • Microorganisms accelerated lignocellulose degradation and humus formation. Understanding large-scale composting under natural conditions is essential for improving waste management and promoting sustainable agriculture. In this study, corn straw (400 tons) and pig manure (200 tons) were composted with microbial inoculants. The thermophilic phase of composting lasted for fourteen weeks, resulting in an alkaline final product. Microbial systems with low-temperature initiation and high-temperature fermentation played a crucial role in enhancing lignocellulose degradation and humic substances (HS) formation. Adding microbes, including Rhodanobacter , Pseudomonas , and Planococcus , showed a positive correlation with degradation rates of cellulose, hemicellulose, and lignin. Bacillus , Planococcus , and Acinetobacter were positively correlated with HS formation. Microorganisms facilitated efficient hydrolysis of lignocelluloses, providing humic precursors to accelerate composting humification through phenolic protein and Maillard pathways. This study provides significant insights into large-scale composting under natural conditions, contributing to the advancement of waste management strategies and the promotion of sustainable agriculture. [ABSTRACT FROM AUTHOR]

[Display omitted] • Diverse species endows SMC with enhanced synergistic activities and adaptability. • The combination of rational and irrational is the trend of future SMC design. • Roles and applications of SMC in biomass wastes treatment are discussed. • SMC is promising in biomass wastes sustainable management and valorization. In response to the persistent expansion of global resource demands, considerable attention has been directed toward the synthetic microbial consortia (SMC) within the domain of microbial engineering, aiming to address the sustainable management and valorization of biomass wastes. This comprehensive review systematically encapsulates the most recent advancements in research and technological applications concerning the utilization of SMC for biomass waste treatment. The construction strategies of SMC are briefly outlined, and the diverse applications of SMC in biomass wastes treatment are explored, with particular emphasis on its potential advantages in waste degradation, hazardous substances control, and high value-added products conversion. Finally, recommendations for the future development of SMC technology are proposed, and prospects for its sustainable application are discussed. [ABSTRACT FROM AUTHOR]

[Display omitted] • Maximal VFAs and hydrogen yields reached 0.66 g/g-VS and 109 mL/g-VS, respectively. • SCG-derived VFAs offer a potential feedstock for microbial protein production. • Candida maltosa KKU-ARY2, a newly isolated yeast, accumulated protein of 43%. • Recycled solid residue after VFAs separation showed a promising methane production. Recovering nutrients from waste for biological processes aligns with sustainability principles. This study aimed to convert spent coffee grounds (SCG) into valuable products, including fermentable sugars, volatile fatty acids (VFAs), yeast-based single-cell protein and biofuels. Alkaline pretreatment was conducted before enzymatic hydrolysis, in which the pretreated SCG was hydrolyzed with varying enzyme loadings (20–60 filter paper units (FPU)/g-solid) and solid loadings (3–15 % w/v). The hydrolyzed slurry was utilized for VFAs and hydrogen production, yielding high values of 0.66 g/g-volatile solids (VS) and 109 mL/g-VS, respectively, using an enzyme loading of 50 FPU/g-solid and a solid loading of 3 % (w/v). The derived VFAs were used to cultivate a newly isolated yeast, Candida maltosa KKU-ARY2, resulting in an accumulated protein content of 43.7 % and a biomass concentration of 4.6 g/L. This study highlights the conversion of SCG into essential components, emphasizing the benefits of waste utilization through cascade bioprocesses. [ABSTRACT FROM AUTHOR]

[Display omitted] • Orange peels was liquefied in sub/supercritical environments without N 2 supply. • The synergetic effects of process parameters promote biocrude's quality and yield. • Biocrude HHV of 38.1 MJ/kg was obtained at 50% ethanol, 430 °C and 35 min. • Biocrude' volatility and molecular weight depends on process variables. • Orange peels is an excellent bioresource material for biocrude production. The efficient valorization of biomass for energy-derived biocrudes is essential for effective waste management. However, the production of biocrudes with high energy and reduced oxygen contents during the liquefaction process requires further insight. Therefore, the impact of reaction temperature, residence time, and ethanol: acetone on the energy compositions and bioproduct's yield enhancement were investigated. The biocrudes obtained were characterized using elemental analysis, GC–MS, FTIR, GPC and TGA to understand the effects of process parameters on the biocrudes' compositions. An improved HHV (38.18 MJ/kg) and lower O/C ratio (0.11) were obtained at 430 °C, 35 min and 50% ethanol with a significant improvement in the enhancement factor, deoxygenation, and percentage hydrogenation of 2.63, 36.88%, and 77.87%, respectively. The presence of ketones, hydrocarbons, phenolics and aromatics of 23.74, 4.28, 37.20 and 17.81% respectively indicate the potential of the obtained biocrude as renewable energy sources upon further upgrading. [ABSTRACT FROM AUTHOR]

The study assessed a co-processing system segregating food waste (FW) with different impurities into liquid (slurry) and solid fractions and treated using anaerobic digestion (AD) and pyrolysis (Py), respectively, which is defined as ADCo-Py. Biomethane potential tests showed higher methane yield from the FW slurry fraction (572.88 mL/gVS FW ) compared to the whole FW (294.37 mL/gVS FW ). Pyrolyzing the FW solid fraction reduced nitrogen compounds in bio-oil by 62 % compared to the whole FW. The energy balance and economic feasibility of ADCo-Py were compared with stand-alone AD, Py, and AD integrated with incineration (ADCo-INC). While all systems required extra energy, stand-alone Py and ADCo-INC needed 3.8 and 2.8 times more energy than ADCo-Py, respectively. Techno-economic analysis favored ADCo-Py, with a net present value (NPV) of $15 million and an internal rate of return (IRR) of 34 %. These findings highlighted FW separation as a promising approach, aligning with energy and economic goals in sustainable FW management., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The circular economy is essential as it encourages the reuse and recycling of resources while reducing waste, which ultimately helps to reduce environmental pollution and boosts economic efficiency. The current review highlights the management of agricultural and livestock residues and their conversion into valuable resources to combat environmental degradation and improve social well-being. The current trends in converting agricultural residues into useful resources emphasize the social benefits of waste management and conversion. It also emphasizes how waste conversion can reduce environmental degradation and enhance food security. Using agricultural residues can increase soil health and agricultural output while reducing pollution, greenhouse gas emissions, and resource depletion. Promoting sustainable waste-to-resource conversion processes requires a combination of strategies that address technical, economic, social, and environmental aspects. These multiple strategies are highlighted along with prospects and considerations., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

• Petroleum residues were effectively removed by Scenedemus abundans. • Spent sorbent was hydrothermally liquefied to yield bio-oil 43.4 wt%. • HTL wastewater recycle showed increase in bio-oil yield (47.91 wt%). • Bio-char possessed 86.5% removal efficiency towards nickel ion. In this study Scenedesmus abundans was used as a biosorbent material for removing hydrocarbons from simulated petroleum wastewater. Batch experiments resulted in the removal of 92.16% of hydrocarbons from simulated wastewater within 60 min. The spent biosorbent was converted to bio-oil through hydrothermal liquefaction process (HTL) at temperature range from 220 to 320 °C with 1 h holding time. Liquid hydrocarbons (bio-oil) yield was 43.4 wt% at 300 °C with 15 g of spent sorbent loading and possessed HHV of 39.10 MJ/Kg. Additionally the HTL wastewater (aqueous phase) was recycled as reaction medium and studied for its effects on bio-oil yield which increased till second cycle (47.91 wt%). HTL bio-char was employed as adsorbent to remove heavy metals from wastewater. It showed greater removal efficiency of 86.5% to Ni(II) ions. From the results it was concluded that the petroleum residues can be effectively recycled back into liquid hydrocarbons with simple waste management pathway. [ABSTRACT FROM AUTHOR]

Highlights • Thermozymes are used in various bioprocesses. • Specific structural features impart them thermostability. • Desirable properties can be imparted to them by use of synthetic biology tools. • Comprehensive research on them helped to increase their application horizons. Abstract In today's scenario of global climate change, there is a colossal demand for sustainable industrial processes and enzymes from thermophiles. Plausibly, thermozymes are an important toolkit, as they are known to be polyextremophilic in nature. Small genome size and diverse molecular conformational modifications have been implicated in devising adaptive strategies. Besides, the utilization of chemical technology and gene editing attributions according to mechanical necessities are the additional key factor for efficacious bioprocess development. Microbial thermozymes have been extensively used in waste management, biofuel, food, paper, detergent, medicinal and pharmaceutical industries. To understand the strength of enzymes at higher temperatures different models utilize X-ray structures of thermostable proteins, machine learning calculations, neural networks, but unified adaptive measures are yet to be totally comprehended. The present review provides a recent updates on thermozymes and various interdisciplinary applications including the aspects of thermophiles bioengineering utilizing synthetic biology and gene editing tools. [ABSTRACT FROM AUTHOR]

Graphical abstract Highlights • Agitated pile composting of flower waste. • Selection of optimum waste combinations using response surface methodology. • Variations in temperature pattern during the composting process. • Availability of nutrients into the compost. Abstract Flower waste (FW) is disposed off in the rivers or mixed with solid waste for landfilling that pollutes the environment and causes harmful effects on human health and aquatic life. It is rich in nutrient content and easily converted into the compost. Therefore, the objective of the present research was to optimize the combinations of flower waste and cow dung during agitated pile composting using response surface methodology. Thirteen different agitated piles were used for composting using the central composite design. The optimum combination from central composite design was 65 kg floral waste, 25 kg cattle dung and 10 kg sawdust having 7.10 pH, 3.31 mS cm−1 electrical conductivity, 32.98% total organic carbon and 14 Carbon to Nitrogen ratio during the end phase of the composting period. The nutrient concentrations into the final compost were within the acceptable limit and also found to be beneficial for the growth of plants. [ABSTRACT FROM AUTHOR]

[Display omitted] • Different technologies for food waste management were investigated for ARG removal. • Thermal treatments (i.e., combustion and pyrolysis) achieved complete ARG removal. • Hyperthermophilic composting achieved partial removal of ARGs. • AnMBR achieved partial removal in the effluent but accumulation in biosolids. • A combination of treatments may be beneficial for food waste ARG removal. The fate of eight different antibiotic resistance genes (ARGs) in food waste (sul1, sul2, tetO, tetW, ermF, ermB, ampC, oxa-1), intI1, and rpoB were monitored during thermal treatment (pyrolysis and incineration), hyperthermophilic composting, and anaerobic membrane bioreactor (AnMBR) treatment. ARGs in food waste ranged from 2.9 × 106 to 3.5 × 109 copies/kg with ampC being the least abundant and sul1 being the most abundant. Thermal treatment achieved removal below detection limits of all ARGs. Only two ARGs (sul1 and ampC) persisted in hyperthermophilic composting. While all genes except for ermB decreased in the AnMBR effluent relative to the food waste feed, sul1 remained at relatively high abundance. Biosolids on the contrary, accumulated tetO, ampC and sul2 in all tested operating conditions. Thermal treatment, despite limited resource recovery, provides the most effective mitigation of ARG risk in food waste. [ABSTRACT FROM AUTHOR]

[Display omitted] • Piggery waste biodegradation using 3 different bulking agents. • Rotary drum composting was accomplished in 20 days. • Thermophilic degradation destructed the E. coli of the feedstock. • Saw dust was proven efficient among tested experimental trials. • Piggery waste composting can be accomplished using only 10% bulking agent. The rapid expansion of the pig industry and the concurrent increase in pig units have posed a significant waste management challenge, particularly in the form of piggery waste. In this study, the potential of three different bulking agents (sawdust, dry leaves, and rice straw) for the biodegradation of piggery waste was evaluated through rotary drum composting (RDC). Following the composting time of 20 days, evaluations of macro and micronutrient concentrations and the C/N ratio revealed stable, matured compost that could be used in farming. However, the saw dust amended RDC (RDC1) outperformed among the studied trails; the total nitrogen content of 1.54%, total phosphorus of 7.68 g kg-1, and total potassium of 23.45 g kg-1 demonstrated the bioproduct produced through RDC1 resulted in superior-quality end product achieved in only 20 days in comparison with other bulking agents studied. Further, the outcomes of the study can serve the swine livestock sector through effective bioconversion of the waste. [ABSTRACT FROM AUTHOR]

[Display omitted] • Greywater derived microalgae used to produce biochar via microwave pyrolysis. • Biochar has high heating value of 28.3 MJ/Kg, comparable to coal. • BET surface area and pore volume of biochar is 121.3 m2/g and 0.3 cc/g. • Fixed carbon and carbon content of biochar increased by 193.6% and 42.3%. • The biofuel production process had a net energy balance of + 11.32 MJ/Kg. Biochar was produced from polyculture microalgae cultivated in greywater using microwave pyrolysis. The highest biochar yield and fixed carbon content of 49.9% and 68.7% were obtained at microwave power (P) of 800 W and reaction time (T) of 8.6 min. The developed quadratic models, 166.96 – 0.23P – 3.87 T – 3.49 x10-3PT + 1.73 x10-4P2 + 0.13 T2 and – 73.79 + 0.29P + 1.86 T – 1.80 x10-4P2 could predict biochar yield and fixed carbon content respectively with errors of 6.2 and 7.9%. The volatile matter (VM), fixed carbon (FC), and high heating value (HHV) of the biomass were 69.2%. 23.4% and 17.6 MJ/Kg, respectively. VM, FC, and HHV for biochar obtained at optimum conditions were 20.2%, 68.7%, and 28.3 MJ/Kg, respectively. The process had a net positive energy balance of 11.32 MJ/Kg and energy efficiency of 1.76. This study paves the way for biochar production from greywater-grown microalgae, contributing to waste valorization and energy sustainability. [ABSTRACT FROM AUTHOR]

[Display omitted] • Ethylene Glycol has no significant effect on biogas yields. • Digester microbiome completely metabolises the ethylene glycol within 28 days. • An increase in microbial diversity is observed after 28 days fermentation. Anaerobic digestion is an established method for the biological conversion of waste feedstocks to biogas and biomethane. While anaerobic digestion is an excellent waste management technique, it can be susceptible to toxins and pollutants from contaminated feedstocks, which may have a detrimental impact on a digester's efficiency and productivity. Ethylene glycol (EG) is readily used in the heat-transfer loops of anaerobic digestion facilities to maintain reactor temperature. Failure of the structural integrity of these heat transfer loops can cause EG to leak into the digester, potentially causing a decrease in the resultant gas yields. Batch fermentations were incubated with 0, 10, 100 and 500 ppm (parts per million) of EG, and analysis showed that the EG was completely metabolised by the digester microbiome. The concentrations of EG tested showed significant increases in gas yields, however there were no significant changes to the digester microbiome. [ABSTRACT FROM AUTHOR]

[Display omitted] • Transition to renewable energy sources is crucial for a sustainable future. • TSAD is a well-established, sustainable technology for waste disposal. • TSAD improves overall recovered energy, process stability, and economic feasibility. • This comprehensive TSAD review emphasizes future utilization of TSAD on a global scale. The transition to renewable energy sources is crucial to ensure a sustainable future. Although the sugar and ethanol industries benefit from this transition, there are untapped opportunities to utilize the waste generated from the sugar and ethanol process chains through two-stage anaerobic digestion (TSAD). This review comprehensively discusses the utilization of various sugarcane-based industrial wastes by TSAD for sequential biohydrogen and methane production. Factors influencing TSAD process performance, including pH, temperature, hydraulic retention time, volatile fatty acids and alkalinity, nutrient imbalance, microbial population, and inhibitors, were discussed in detail. The potential of TSAD to reduce emissions of greenhouse gases is demonstrated. Recent findings, implications, and promising future research related to TSAD, including the integration of meta -omics approaches, gene manipulation and bioaugmentation, and application of artificial intelligence, are highlighted. The review can serve as important literature for the implementation, improvement, and advancements in TSAD research. [ABSTRACT FROM AUTHOR]

[Display omitted] • Microbial pretreatment produces more reducing sugar than chemical pretreatment. • Bacillus oryzaecorticis has more influence on OH and COOH of FA structure. • Bacillus licheniformis contributed more to the aliphatic structure of HA. The study aimed to investigate the pretreatment characteristics of food waste (FW) by Bacillus licheniformis and Bacillus oryzaecorticis , and to determine the contribution of microbial hydrolysis in the structure of fulvic acid (FA) and humic acid (HA). FW was pretreated with Bacillus oryzaecorticis (FO) and Bacillus licheniformis (FL), and the resulting solution was heated to synthesize humus. The results showed that the acidic substances produced by microbial treatments led to a decrease in pH. In addition, Bacillus oryzaecorticis degraded starch and released a large amount of reducing sugar, providing OH and COOH to FA molecules. Bacillus licheniformis showed a positive effect on the HA structure, which had higher OH, CH 3 and aliphatics. FO is more beneficial to retain OH and COOH, while FL is more beneficial to retain amino and aliphatics. This study provided evidence for the application of Bacillus licheniformis and Bacillus oryzaecorticis in waste management. [ABSTRACT FROM AUTHOR]

[Display omitted] • α-etherification of β-O-4 linkage in lignin by alcohols protect it from degradation. • Long-chain mono/dihydric alcohols generally lead to higher β-O-4-rich lignin yield. • Alcohol-based acidic DES as green solvents for β-O-4-rich lignin extraction. • Flow-through and microwave-assisted alcohol fractionation as emerging technologies. • Effective recovery of alcohols with high boiling point presents as major challenge. Utilizing lignocellulosic biomass wastes to produce bioproducts is essential to address the reliance on depleting fossil fuels. However, lignin is often treated as a low-value-added component in lignocellulosic wastes. Valorization of lignin into value-added products is crucial to improve the economic competitiveness of lignocellulosic biorefinery. Monomers obtained from lignin depolymerization could be upgraded into fuel-related products. However, lignins obtained from conventional methods are low in β-O-4 content and, therefore, unsuitable for monomer production. Recent literature has demonstrated that lignins extracted with alcohol-based solvents exhibit preserved structures with high β-O-4 content. This review discusses the recent advances in utilizing alcohols to extract β-O-4-rich lignin, where discussion based on different alcohol groups is considered. Emerging strategies in employing alcohols for β-O-4-rich lignin extraction, including alcohol-based deep eutectic solvent, flow-through fractionation, and microwave-assisted fractionation, are reviewed. Finally, strategies for recycling or utilizing the spent alcohol solvents are also discussed. [ABSTRACT FROM AUTHOR]

Biochar production through thermochemical processing is a sustainable biomass conversion and waste management approach. However, commercializing biochar faces challenges requiring further research and development to maximize its potential for addressing environmental concerns and promoting sustainable resource management. This comprehensive review presents the state-of-the-art in biochar production, emphasizing quantitative yield and qualitative properties with varying feedstocks. It discusses the technology readiness level and commercialization status of different production strategies, highlighting their environmental and economic impacts. The review focuses on integrating machine learning algorithms for process control and optimization in biochar production, improving efficiency. Additionally, it explores biochar's environmental applications, including soil amendment, carbon sequestration, and wastewater treatment, showcasing recent advancements and case studies. Advances in biochar technologies and their environmental benefits in various sectors are discussed herein., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Highlights • Three models were applied to identify the main fouling mechanisms in a UF membrane. • Surface fouling had the best fits for the blocking laws and combined models. • In all cases similar fits were obtained with both models when N 2 bubbling was applied. • There are clear differences between filtration runs with and without gas bubbling. • The resistance-in-series model identified a post-cake fouling mechanism. Abstract Three models (blocking laws, combined and resistance-in-series) were applied to identify the prevailing fouling mechanisms in a submerged membrane in an up-flow anaerobic sludge blanket reactor treating municipal wastewater. Experimental runs were carried out at lab-scale with filtration periods of 4 and 10 min, followed by relaxation periods of one minute with and without nitrogen bubbling. In all conditions excepting one (IF4R), the blocking laws model showed a predominance of cake formation. With the combined model, cake formation coupled with intermediate, standard and complete fouling had the better fits in all conditions, excepting IF4 and IF4R. When sewage was fed, both models pointed at intermediate fouling in the absence of gas bubbling. The resistance-in-series model identified the positive effect of gas bubbling and a post-cake fouling behavior, not shown by the other two models. This modeling approach could be applied for achieving longer filtration runs in submerged UF membranes. [ABSTRACT FROM AUTHOR]

Electro-dewatering (ED) pretreatment could improve sludge dewatering performance and remove heavy metal, but the effect of ED pretreatment on nitrous oxide (N 2 O) emission and related functional genes in sludge composting process is still unknown, which was firstly investigated in this study. The results revealed that ED pretreatment changed the physicochemical characteristics of sludge and impacted N 2 O related functional genes, resulting in the reduction of cumulative N 2 O emission by 77.04% during 60 days composting. The higher pH and NH 4 + -N, but lower moisture, ORP and NO 2 − -N emerged in the composting of ED sludge compared to mechanical dewatering (MD) sludge. Furthermore, ED pretreatment reduced amoA , hao , narG , nirK and nosZ in ED sludge on Day-10 and Day-60 of composting. It was found that nirK reduction was the major factor impacting N 2 O generation in the initial composting of ED sludge, and the decline of amoA restricted N 2 O production in the curing period. [ABSTRACT FROM AUTHOR]

The effect of calcium peroxide (CaO 2 ) addition on anaerobic digestion (AD) of waste activated sludge (WAS) at different temperatures (20 °C, 35 °C, and 55 °C) were investigated. The results show that CaO 2 addition had significant positive effect on short-chain fatty acids (SCFAs) production under ambient and mesophilic conditions. Polysaccharides and proteins embedded in extracellular polymeric substances (EPS) were effectively released from inner fraction to outer fraction, and non-biodegradable humic-like substances were decreased while easily biodegradable tryptophan-like proteins increased. These effects were most remarkable under ambient conditions. However, CaO 2 addition was unfavorable to thermophilic AD because of high free ammonia concentrations and the accumulation of humic-like substances. Temperature showed a stronger effect than CaO 2 on microbial community structure, but CaO 2 addition was more effective than temperature in enhancing hydrolytic and acidifying microorganisms. Predictive functional profiling indicated that microbial hydrolysis, metabolism and acidification were promoted by CaO 2 under ambient conditions. [ABSTRACT FROM AUTHOR]

Petroleum industry is one of the largest and fast growing industries due to the ever increasing global energy demands. Petroleum refinery produces huge quantities of wastes like oily sludge, wastewater, volatile organic compounds, waste catalyst, heavy metals, etc., because of its high capacity and continuous operation of many units. Major challenge to this industry is to manage the huge quantities of waste generated from different processes due to the complexity of waste as well as changing stringent environmental regulations. To decrease the energy loss for treatment and also to conserve the energy stored in the chemical bonds of these waste organics, bio-electrochemical system (BES) may be an efficient tool that reduce the economics of waste disposal by transforming the waste into energy pool. The present review discusses about the feasibility of using BES as a potential option for harnessing energy from different waste generated from petroleum refineries. [ABSTRACT FROM AUTHOR]

Mixotrophic denitrification coupled biological denitrification with iron and carbon micro-electrolysis (IC-ME) is a promising emerging bioprocess for nitrate removal of biologically enhanced treated coal gasification wastewater (BECGW) with low COD to nitrate ratio. TN removal efficiency in R1 with IC-ME assisted was 16.64% higher than R2 with scrap zero valent iron addition, 23.05% higher than R3 with active carbon assisted, 30.51% higher than R4 with only active sludge addition, 80.85% higher than R5 utilizing single IC-ME as control. Fe 2+ generated from IC-ME decreased the production of N 2 O and enriched more Nitrate-reducing Fe(Ⅱ) oxidation bacteria (NRFOB) Acidovorax and Thiobacillus , which could convert nitrate to nitrogen gas. And the presence of Fe 3+ , as the Fe 2+ oxidation product, could stimulate the growth of Fe(III)-reducing strain (FRB) that indicated by redundancy analysis. Microbial network analysis demonstrated FRB Geothrix had a co-occurrence relationship with other bacteria, revealing its dominant involvement in nitrate removal of BECGW. [ABSTRACT FROM AUTHOR]

The anaerobic treatment of leachate from a municipal waste transfer station in Malaysia was tested using a pilot scale anaerobic biofilm digester system that was operated under HRT sequence of 30-day, 25-day, 20-day and 10-day for 163 days under mesophilic conditions. Despite the leachate’s complex characteristics, the system showed great performance given its maximum COD, BOD 5 and total phosphorus removal efficiencies of 98 ± 1%, 99 ± 1% and 92 ± 9% respectively. The system was stable throughout its operation and showed optimal average values for the monitored parameters such as pH (7.53 ± 0.14), total VFA (79 ± 66 mg HOAc/L), alkalinity (10,919 ± 1556 mg CaCO 3 /L) and a non-toxic value for accumulated ammonia (960 ± 106 mg NH 3 -N/L). Measurement of the average daily biogas production yielded a value of 25 ± 1 m 3 /day throughout the system’s operation with a composition of 57 ± 12% methane and 26 ± 6% carbon dioxide. [ABSTRACT FROM AUTHOR]

This study investigates the pyrolysis of Medium Density Fiberboard (MDF) as a potential waste management solution. Thermal behaviour of MDF was analysed via TG/DSC. The primary decomposition step occurred between 190 °C and 425 °C. Evolved gaseous products over this step were evaluated by a FTIR spectrometer coupled with TGA. Peaks for phenolic, alcohols and aldehydes were detected at the maximum decomposition temperature. Py-GC/MS analysis revealed phenols, ketones and cyclic compounds as the primary non-condensable pyrolysis products. The kinetics of pyrolysis were investigated by the widely applied Distributed Activation Energy Model, resulting in an average activation energy and pre-exponential factor of 127.40 kJ mol −1 and 8.4E+11. The results of this study suggest that pyrolyzing MDF could potentially provide renewable fuels and prevent environmental problems related with MDF disposal. [ABSTRACT FROM AUTHOR]

In the current study, the feasibility of utilizing municipal secondary wastewater sludge for Polyhydroxyalkanoate (PHA) extraction was improved by optimization of various parameters (temperature, duration and concentration of sludge solids). Optimized process parameters resulted in PHA recovery of 0.605 g, significantly higher than un-optimized conditions. The characterization of PHA was carried out by GC–MS, FT-IR and NMR ( 1 H and 13 C) spectroscopy. The PHA profile was found to be dominated by mcl PHA (58%) along with other diverse PHA. The results of the present study show rich diversity of PHA extracted from a raw material which is readily available at minimal cost. In conclusion, exploring the potential of wastes for production of bioplastics not only reduces the cost of bioplastic production, but also provides a sustainable means for waste management. [ABSTRACT FROM AUTHOR]

The applicability of slurry-based (semi-liquids) BMP assay in determining biodegradation kinetic parameters of landfilled waste is critically reviewed. Factors affecting the amount and rate of methane (CH 4 ) production during anaerobic degradation of municipal solid waste (MSW) and optimal values of these factors specific to landfill conditions are presented. The history of conventional BMP, and some existing procedures are reviewed. A landfill BMP (LBMP) assay is proposed that manipulates some of the key factors, such as moisture content, particle and sample size, that affects the rate of CH 4 production and the CH 4 generation potential of landfilled MSW (LMSW). By selecting proper conditions for these factors, a representative BMP assay could be conducted to ensure accurate determinations of CH 4 potential and the kinetic parameters k; first order rate coefficient and L o ; methane generation potential. [ABSTRACT FROM AUTHOR]

The source segregated vegetable waste (VW) was used as main feedstock and locally available organic wastes, such as water hyacinth (WH), garden prune (GP) and sawdust (SD) were used as bulking agents (BAs) to make the compost stable and mature in combination with cow dung (CD) as a source of inoculant. Three trials (T 1 , T 2 & T 3 ) were performed with a compost ratio of 6:3:1 (VW:BA:CD) using different BAs. The initial C/N ratio of all the trials was maintained lesser than 23 and composted for 30 days (7 days in rotary drum reactor + 23 days windrowing). The ANOVA analysis indicated that the physico-chemical parameters varied significantly (p < .05) with the time of composting. It was also indicated that SD is the most performing BA for North-eastern region of India due to optimum germination index of 110% along with leachate management. [ABSTRACT FROM AUTHOR]

This study presents a preliminary assessment of biodiesel production from waste sources available in the Kingdom of Saudi Arabia (KSA) for energy generation and solution for waste disposal issues. A case study was developed under three different scenarios: (S1) KSA population only in 2017, (S2) KSA population and pilgrims in 2017, and (S3) KSA population and pilgrims by 2030 using the fat fraction of the municipal solid waste. It was estimated that S1, S2, and S3 scenarios could produce around 1.08, 1.10 and 1.41 million tons of biodiesel with the energy potential of 43423, 43949 and 56493 TJ respectively. Furthermore, annual savings of US $55.89, 56.56 and 72.71 million can be generated from landfill diversion of food waste and added to the country’s economy. However, there are challenges in commercialization of waste to biodiesel facilities in KSA, including waste collection and separation, impurities, reactor design and biodiesel quality. [ABSTRACT FROM AUTHOR]

When adsorption is considered for water treatment, commercial activated carbon is usually the chosen adsorbent for the removal of pollutants from the aqueous phase, particularly pharmaceuticals. In order to decrease costs and save natural resources, attempts have been made to use wastes as raw materials for the production of alternative carbon adsorbents. This approach intends to increase efficiency, cost-effectiveness, and also to propose an alternative and sustainable way for the valorization/management of residues. This review aims to provide an overview on waste-based adsorbents used on pharmaceuticals’ adsorption. Experimental facts related to the adsorption behaviour of each adsorbent/pharmaceutical pair and some key factors were addressed. Also, research gaps that subsist in this research area, as well as future needs, were identified. Simultaneously, this review aims to clarify the current status of the research on pharmaceuticals’ adsorption by waste-based adsorbents in order to recognize if the right direction is being taken. [ABSTRACT FROM AUTHOR]

Hydrothermal carbonization (HTC) of sweet potato waste was performed to investigate the effect of process parameters including reaction temperature (180–300 °C) and residence time (0–120 min) on the characteristics of hydrochars. The results showed that the increase of reaction temperature and residence time both decreased the yield of hydrochars. With the increase of reaction temperature and residence time, the carbon content of hydrochars increased, while the hydrogen and oxygen contents decreased. The lower H/C and O/C ratios indicated that dehydration and decarboxylation reactions occurred during HTC. The occurrence of aromatization reaction was found in FTIR spectra. Thus, the fixed carbon content, higher heating value, and energy density of hydrochars increased. SEM analysis indicated that HTC developed rough surface with crack on the hydrochars. The thermogravimetric experiments displayed the increase trend in combustion ignition temperature, burnout temperature and activation energy as reaction temperature and time increase, which showed better combustion characteristics. [ABSTRACT FROM AUTHOR]

Food waste (FW) management by biological process is more attractive and eco-friendly approach than thermo-chemical conversion or landfilling. However, FW composition and physico-chemical and biological characteristics affect the overall biological process in terms of product yield and degradation rate. To overcome this major bottle-neck, the pretreatment of FW is proposed. Therefore this review aims to provide a comprehensive summary of the importance of pretreatment of FW with respect to FW management by anaerobic digestion (AD) and dark fermentation (DF). It also reviews the existing knowledge gaps and future research perspectives for better integration of FW pretreatments for AD and DF, which should include (i) the preservation of carbon mass through freeze and thaw, or drying; and (ii) improve the carbon accessibility through particle size reduction and thermal pretreatments for high-rate bioenergy recovery. [ABSTRACT FROM AUTHOR]

In this study, mixed microalgae consortia was cultivated using digestate (D), animal manure (AM) and textile wastewater (TW) as growth medium providing mainly N (nitrogen) and P (phosphorous) sources without any extra nutrient addition. The corresponding total nitrogen (TN) and total phosphorous (TP, PO3-P) concentrations were noted as 323 and 21 for AM, 481 and 31 for TW and 747 and 55 mg/L for D, respectively. After a cultivation period of 13 days, P were completely removed (100%), however, N was still remain and attained the removal rate of 70.1, 72.3 and 16.7% for TW, AM and D, respectively. The peak growth rate and biomass production of 0.419 d −1 and 0.4 g/L (in terms of volatile solids, VS) was achieved using TW as growth medium. [ABSTRACT FROM AUTHOR]

Anaerobic digestion (AD) is a mature technology that can transform organic matter into a bioenergy source – biogas (composed mainly of methane and carbon dioxide), while stabilizing waste. AD implementation around the world varies significantly, from small-scale household digesters in developing countries to large farm-scale or centralized digesters in developed countries. These differences in the implementation of AD technology are due to a complex set of conditions, including economic and environmental implications of the AD technology, and stimulus provided by a variety of polices and incentives related to agricultural systems, waste management, and renewable energy production. This review explores the current status of the AD technology worldwide and some of the environmental, economic and policy-related drivers that have shaped the implementation of this technology. The findings show that the regulations and incentives have been the primary factor influencing the steady growth of this technology, in both developing and developed countries. [ABSTRACT FROM AUTHOR]

The study investigated the influence of the target pH-values 4.5, 5, 5.5 and 6 in the acidification reactor on process parameters, such as substrate-specific methane yield and the intermediates, in the two-stage anaerobic digestion of sugar beet silage. The total specific methane yield (Nl kg −1 COD d −1 ) increased with an increase in the pH (pH 4.5: 140.58 ± 70.08, pH 5: 181.21 ± 55.71, pH 5.5: 218.32 ± 51.01, pH 6: 256.47 ± 28.78). The pH-value also had an effect on the dominant intermediate in hydrolysate. At the pH-value of 4.5, almost no acidification and microbial activity was observed. At pH 5 and 5.5, butyric acid production dominated, guided by H 2 production. At pH 6 acetic acid was the main product. The absence of H 2 and the highest SMY makes it favorable under practical aspects. [ABSTRACT FROM AUTHOR]

This study evaluated the potential of energy generation using a combined heat and power co-generation system (CHP) from biogas produced during the anaerobic digestion of coffee husks (CH) pretreated with steam explosion. Pretreatment conditions assessed were time (1, 5, 15 and 60 min) and temperature (120, 180 and 210 °C). Polysaccharides solubilisation and biogas production were not correlated. While pretreatment with severities higher than 4 resulted in a highest solubilisation of cellulose, hemicelluloses and lignin; however, furans concentration in those cases hindered biomass biodegradation. Considering a CHP, all pretreatment conditions were worthwhile when compared to non-pretreated CH. The best condition was 120 °C for 60 min, in which a 2.37 severity showed the highest methane yield (144.96 NmL CH 4 g COD −1 ) and electricity production (0.59 kWh kg CH −1 ). However, even better results could be achieved using 120 °C for only 5 min, which would lead to a larger amount of CH daily processed. [ABSTRACT FROM AUTHOR]

Effect of single-function (oil degrading) and multi-functional bacterial consortium with zeolite as additive for post-consumption food waste (PCFW) composting was investigated through assessing the oil content reduction in a computer controlled 20-L composter. Three treatments of PCFWs combined with 10% zeolite were developed: Treatment-2 and Treatment-3 were inoculated with multi-functional (BC-1) and oil degrading bacterial consortium (BC-2), respectively, while T-1 was without bacterial inoculation and served as control. Results revealed that BC-2 inoculated treatment (T-3) was superior to control treatment and marginally better than T-2 in terms of oil degradation. The reduction of oil content was >97.8% in T-3 and 92.27% in T-2, while total organic matter degradation was marginally higher in T-2 (42.95%) than T-3 (41.67%). Other parameters of compost maturity including germination test indicated that T-2 was marginally better than T-3 and significantly enhanced the oily PCFW decomposition and shortened the composting period by 20 days. [ABSTRACT FROM AUTHOR]

Waste generation is increasing day-by-day with the growth of population which directly affects the environment and economy. Organic municipal solid waste (MSW) and agriculture sectors contribute towards maximum waste generation in India. Thus, management of organic waste is very much essential with the increasing demand for energy. The present paper mainly focusses on reviewing waste to energy (WtE) potentials, its technologies, and the associated challenges. Different substrates are utilized through various technological options in India. Organic waste has good potential to attain sustainable energy yields with and without affecting the environment. A realistic scenario of WtE technologies and their challenges in line with the existing Indian condition is presented in this paper. [ABSTRACT FROM AUTHOR]

Valorisation of bread waste for hydroxymethylfurfural (HMF) synthesis was examined in dimethyl sulfoxide (DMSO)-, tetrahydrofuran (THF)-, acetonitrile (ACN)-, and acetone-water (1:1 v/v), under heating at 140 °C with SnCl 4 as the catalyst. The overall rate of the process was the fastest in ACN/H 2 O and acetone/H 2 O, followed by DMSO/H 2 O and THF/H 2 O due to the rate-limiting glucose isomerisation. However, the formation of levulinic acid (via rehydration) and humins (via polymerisation) was more significant in ACN/H 2 O and acetone/H 2 O. The constant HMF maxima (26–27 mol%) in ACN/H 2 O, acetone/H 2 O, and DMSO/H 2 O indicated that the rates of desirable reactions (starch hydrolysis, glucose isomerisation, and fructose dehydration) relative to undesirable pathways (HMF rehydration and polymerisation) were comparable among these mediums. They also demonstrated higher selectivity towards HMF production over the side reactions than THF/H 2 O. This study differentiated the effects of polar aprotic solvent-water mediums on simultaneous pathways during biomass conversion. [ABSTRACT FROM AUTHOR]

[Display omitted] • Waste-to-energy for municipal solid waste management have been presented. • Effective waste management requires integrated technologies. • Artificial intelligence helps to develop a sustainable waste management technique. • Policy, economic and environmental impact analysis reduces the risk. The consumption of energy levels has increased in association with economic growth and concurrently increased the energy demand from renewable sources. The need under Sustainable Development Goals (SDG) intends to explore various technological advancements for the utilization of waste to energy. Municipal Solid Waste (MSW) has been reported as constructive feedstock to produce biofuels, biofuel carriers and biochemicals using energy-efficient technologies in risk freeways. The present review contemplates risk assessment and challenges in sorting and transportation of MSW and different aspects of conversion of MSW into energy are critically analysed. The circular bioeconomy of energy production strategies and management of waste are also analysed. The current scenario on MSW and its impacts on the environment are elucidated in conjunction with various policies and amendments equipped for the competent management of MSW in order to fabricate a sustained environment. [ABSTRACT FROM AUTHOR]