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[Display omitted] • Biochemical content increased at the expense of biomass production. • CO 2 at 5% produced 4% more carbohydrates but at a 50% reduction of Chlorella biomass. • Carotenoids contents increased at the cost of 32% reduced Nostoc biomass production. • CO 2 at 10% significantly promoted protein, carbohydrate and lipids in Chlamydomonas. Microalgae's exceptional photosynthetic prowess, CO 2 adaptation, and high-value bioproduct accumulation make them prime candidates for microorganism-based biorefineries. However, most microalgae research emphasizes downstream processes and applications rather than fundamental biomass and biochemical balances and kinetic under the influence of greenhouse gases such as CO 2. Therefore, three distinctly different microalgae species were cultivated under 0% to 20% CO 2 treatments to examine their biochemical responses, biomass production and metabolite accumulations. Using a machine learning approach, it was found that Chlorella sorokiniana showed a positive relationship between biomass and chl a, chl b, carotenoids, and carbohydrates under increasing CO 2 treatments, while Chlamydomonas angulosa too displayed positive relationships between biomass and all studied biochemical contents, with minimal trade-offs. Meanwhile, Nostoc sp. exhibited a negative correlation between biomass and lipid contents under increasing CO 2 treatment. The study showed the potential of Chlorella , Chlamydomonas and Nostoc for commercialization in biorefineries and carbon capture systems where their trade-offs were identified for different CO 2 treatments and could be prioritized based on commercial objectives. This study highlighted the importance of understanding trade-offs between biomass production and biochemical yields for informed decision-making in microalgae cultivation, in the direction of mass carbon capture for climate change mitigation. [ABSTRACT FROM AUTHOR]

• Crop residue-derived biochar production reduces global warming potential. • The feedstock composition and pyrolysis temperature strongly regulate biochar yields. • Slow pyrolysis and microwave-assisted pyrolysis suitable for biochar production. • Physical and chemical properties of biochar are critically discussed. • The concept of biochar, bio-oil, and gas nexus is important for sustainability. Worldwide surge in crop residue generation has necessitated developing strategies for their sustainable disposal. Pyrolysis has been widely adopted to convert crop residue into biochar with bio-oil and gas being two co-products. The review adopts a whole system philosophy and systematically summarises up-to-date knowledge of crop residue pyrolysis processes, influential factors, and biochar applications. Essential process design tools for biochar production e.g., cost-benefit analysis, life cycle assessment, and machine learning methods are also reviewed, which has often been overlooked in prior reviews. Important aspects include (a) correlating techno-economics of biochar production with crop residue compositions, (b) process operating conditions and management strategies, (c) biochar applications including soil amendment, fuel displacement, catalytic usage, etc., (d) data-driven modelling techniques, (e) properties of biochar, and (f) climate change mitigation. Overall, the review will support the development of application-oriented process pipelines for crop residue-based biochar. [ABSTRACT FROM AUTHOR]

[Display omitted] • Midpoint and endpoint environmental profiles for bio-based isobutene are performed. • Pre-treatment represents the largest environmental burden due to steam demand. • From a system approach, co-produce lignin increases the impacts of the biorefinery. • In a product point view, the isobutene profile benefits sharing impacts with lignin. • Allocation method is a relevant decision to declare an environmental profile product. Moving toward a bioeconomy system is fundamental to climate change mitigation, nevertheless, the biotechnological routes should guarantee an environmental sustainability. Isobutene, a precursor in several industrial applications, is one of those chemicals that the environmental effects of its bio-based production have been scarcely explored. This study aims to assess the environmental performance of two biorefinery systems: the first one focuses only on the production of isobutene (I) and the second one on the co-production with lignin (I + L), both from the valorisation of wheat straw. The Life Cycle Assessment methodology is used to determine the environmental impacts considering mid-point and end-point categories. Biorefineries report 0.65 and 1.32 kg CO 2 -eq per kg of biomass processed for I and I + L system, respectively. The most affected endpoint damage category corresponds to Human Health, regardless of the scenarios. Moreover, the pre-treatment stage constitutes the main hotspot of both systems considering midpoint and endpoint perspectives. [ABSTRACT FROM AUTHOR]

The mitigation of greenhouse gas (GHG) emission is one of the major focuses of The Glasgow Climate Pact, a global agreement that is believed to accelerate climate action. Following the energy sector, industrial and agro-wastes are the major contributors to global GHG emission. With the rapid growth in population, affluence, and urbanization, the GHG emission from waste sector is likely to be further aggravated if timely measures are not taken to address this burning issue. Thus, a significant research and development efforts are being made in shifting conventional waste treatment approach to resource recovery from waste, incorporating a circular bioeconomy concept. There have been significant advances in technologies such as anaerobic digestion, composting, pyrolysis, algae farming, and microbial fuel cell for recovering resources from organic wastes. This virtual special issue (VSI), "Bioconversion of Waste-to-Resources (BWR-2021)", contains 25 manuscripts covering various aspects of wastes and residual biomass valorization to high value products, including development of new technologies, optimization of current technologies for more efficient utilization of wastes and residues. The key findings of each manuscript are briefly summarized here, which can serve as a valuable resource for researchers in the field of resource recovery from wastes. [ABSTRACT FROM AUTHOR]

• Microalgae make use of carbon-dioxide to produce biomass and biomolecules. • Cell wall weakening followed by disintegration has positive impact on product recovery. • The energy and economic benefits of cell wall weakening as pre-treatment is detailed. Microalgae is considered as a renewable and sustainable biomass to produce bioenergy and other high-value products. Besides, the cultivation of microalgae does not need any fertile land and it provides opportunities for climate change mitigation by sequestering atmospheric carbon-dioxide (CO 2), facilitating nutrient recovery from wastewater and regulating industrial pollutions/emissions. Algal biomass harvested from different technologies are unique in their physio-chemical properties that require critical understanding prior to value-addition or bioenergy recovery. In this review, we elaborate the importance of cell wall weakening followed by pretreatment as a key process step and strategy to reduce the energy cost of converting algal biomass into bioenergy. From the energy-calculations, it was measured that the cell wall weakening significantly improves the net-energy ratio from 0.68 to 1.02. This approach could be integrated with any pre-treatment options, while it reduces the time of pre-treatment and costs of energy/chemicals required for hydrolysis of algal biomass. [ABSTRACT FROM AUTHOR]

• Bioregenerative ecosystem is a sustainable strategy for global life essentials. • Species configurations need to be streamlined based on the current knowledge. • Mitigation of climate change and urban farming are two major applications of BLSS. • Integrating waste biorefineries and solar energy could achieve circular bioeconomy. Climate change, resource depletion and unsustainable crop productivity are major challenges that mankind is currently facing. Natural ecosystems of earth's biosphere are becoming vulnerable and there is a need to design Bioregenerative Life Support Systems (BLSS) which are ecologically engineered microcosms that could effectively deal with problems associated with urbanization and industrialization in a sustainable manner. The principles of BLSS could be integrated with waste fed biorefineries and solar energy to create a self-sustainable bioregenerative ecosystem (SSBE). Such engineered ecosystems will have potential to fulfil urban life essentials and climate change mitigation thus generating ecologically smart and resilient communities which can strengthen the global economy. This article provides a detailed overview on SSBE framework and its improvement in the contemporary era to achieve circular bioeconomy by means of effective resource recycling. [ABSTRACT FROM AUTHOR]

• Bioregenerative ecosystem is a sustainable strategy for global life essentials. • Species configurations need to be streamlined based on the current knowledge. • Mitigation of climate change and urban farming are two major applications of BLSS. • Integrating waste biorefineries and solar energy could achieve circular bioeconomy. Climate change, resource depletion and unsustainable crop productivity are major challenges that mankind is currently facing. Natural ecosystems of earth's biosphere are becoming vulnerable and there is a need to design Bioregenerative Life Support Systems (BLSS) which are ecologically engineered microcosms that could effectively deal with problems associated with urbanization and industrialization in a sustainable manner. The principles of BLSS could be integrated with waste fed biorefineries and solar energy to create a self-sustainable bioregenerative ecosystem (SSBE). Such engineered ecosystems will have potential to fulfil urban life essentials and climate change mitigation thus generating ecologically smart and resilient communities which can strengthen the global economy. This article provides a detailed overview on SSBE framework and its improvement in the contemporary era to achieve circular bioeconomy by means of effective resource recycling. [ABSTRACT FROM AUTHOR]

• Need for agri-waste derived biogas based circular economy has been discussed. • Anaerobic digestion is a promising technology for agri-waste valorisation in India. • Valorization of products of anaerobic digestion for circular economy has been discussed. • Barriers in supply chain and technical knowledge impede growth of circular economy. • Requirement of efficient implementation of policy and regulatory framework exists. Environmental deterioration and the need for energy security are intrinsic problems linked with the linear economy based on fossil fuels. Recently, a transformation to a sustainable circular bio-economy is being experienced where biomass waste is being valorized for energy production as well as minimization of waste and greenhouse gas emissions. The agricultural waste, generated in vast quantities in India is a prospective feedstock for biogas production. Agri-waste to biogas based circular economy requires an integration of agri-waste management, biogas production and utilization and policy support. This paper comprehensively discusses the potential of biogas production from agricultural waste, its upgradation and utilization along with the government initiatives, policy regulations. In addition, barriers that impede the development of an efficient agri-waste to biogas based circular economy, and the future research opportunities to meet the growing needs for agri-waste management, energy production and climate change mitigation are discussed. [ABSTRACT FROM AUTHOR]

• The removal of AOX was improved in a biochar-amended AnMBR. • Fouling mitigation was achieved in 'TMP jump' stage with biochar addition. • The major foulant EPS-protein was sharply reduced with biochar addition. • High Mw EPS-proteins in cake layer were degraded into low Mw proteins. • The relative abundance of bio-foulant Arcobacter decreased obviously. Anaerobic membrane bioreactor (AnMBR) is an advanced technology in treating pharmaceutical wastewater, but the membrane fouling limits its development. In this study, the biochar with adsorption capacity of biopolymers was added in AnMBR to investigate its potential in treating pharmaceutical wastewater and alleviating membrane fouling. In the biochar-amended AnMBR, adsorbable organic halogen (AOX) was removed effectively, and more COD was biotransformed into CH 4. Membrane fouling mitigation was achieved in the third stage with a 56% decrease of average transmembrane pressure difference (TMP) rising rate. The predominant culprit, proteins of extracellular polymeric substance (EPS-proteins) in sludge mixture and cake layer, was reduced significantly. Particularly, the proportion of micromolecular (0.1–0.15 kDa) EPS-proteins in cake layer was 1.5-folds that of the control group. The important bio-foulant genus Arcobacter aggregating on the membrane had less and almost half the relative abundance (16.5%) than that of the control group (30.7%). [ABSTRACT FROM AUTHOR]