1. Clean syngas from biomass—process development and concept assessment
- Author
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Johanna Kihlman, Matti Nieminen, Pekka Simell, Sanna Tuomi, Noora Kaisalo, Ilkka Hiltunen, Esa Kurkela, and Ilkka Hannula
- Subjects
Waste management ,Methane reformer ,Renewable Energy, Sustainability and the Environment ,Chemistry ,tar reforming ,gasification ,Biomass ,Tar ,Methane ,Liquid fuel ,chemistry.chemical_compound ,Catalytic reforming ,gas clean-up ,Small stationary reformer ,techno-economic evaluation ,hot gas filtration ,Syngas - Abstract
This paper summarises the long development work done at VTT for gas clean-up for various synthesis applications. The development work has covered the most challenging and costly steps in biomass gasification based processes: high-temperature gas filtration and reforming of hydrocarbon gases and tars. The tar content of product gas is one of the main factors defining the temperature window in which the hot-gas filter can be operated, which in the case of fluidized-bed gasification is at 350–500 °C. Research is ongoing to achieve higher and thus more economical operation temperatures. Optimal operation of a catalytic reformer can be achieved by using a staged reformer where zirconia-based catalysts are used as a pre-reformer layer before nickel and/or precious metal-based catalyst stages. The temperature of the reformer is optimally increased in subsequent stages from 600 up to 1,000 °C. According to the techno-economic analysis, increasing the hot-gas filtration temperature by 300 °C or methane conversion in the reformer from 55 to 95 % both lead to about 5 % reduction the liquid fuel production cost.
- Published
- 2014
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