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The primary objective of this study was to assess the feasibility of utilizing urine-prepared NaOH solution (NUr) as an innovative pretreatment approach for enhancing BHP in rice straw through anaerobic digestion (AD) process. The findings suggest that pretreatment with NUr could substantially enhance hydrolysis rates and H 2 production. The maximum biohydrogen production (BHP) yield reached 184.46 mL/g substrate with 86.98 % holocellulose retention yield and 59.84 % removal of lignin when RS was pretreated by NUr at a concentration of 3 % w/v, 20 % solid loading, −12 °C, and 3 months. Macro and microstructure analysis confirmed more cellulose and hemicellulose were exposed due to the lignin removed, and crystallinity decreased after NUr pretreatment. The energy conversion efficiency (ECE) attained via NUr pretreated RS was 10.38 %, exceeded that of raw RS by 62.19 %. These findings offer a promising and efficient pretreatment technology for enhancing the recovery of H 2 from lignocellulosic biomass, yielding both environmental and economic advantages. [Display omitted] • The maximum bio-H 2 production from RS reached 184.46 mL/g substrate by NUr pretreatment. • NUr pretreatment could achieve 86.98 % holocellulose retention and 59.84 % removal of lignin. • NUr pretreatment improves the biohydrogen potential (B 0) of RS by 91.86 %. • NUr pretreatment improves hydrolysis rate (k) of RS by 37.04 %. • Material balance and ECE analysis suggested NUr is an attractive pretreatment method. [ABSTRACT FROM AUTHOR]

Recirculation of hydrothermal carbonization (HTC) process water (PW) has been revealed as an effective strategy to promote the recovery of lost dissolved organics in the spent solvent. However, the role of operating parameters such as temperature, time and solid load during recirculation needs to be clarified and better investigated in order to achieve a successful PW valorization. In this paper, the effects of different reaction conditions during HTC with PW recirculation were studied by using orange peel waste as feedstock. The results showed that strong synergistic interactions occurred between the biomass and the recycled solvent, leading to a hydrochar mass yield increase between 0.5 and 11 wt% on a dry basis (d.b.), according to the reaction conditions. PW recirculation, especially at low conversion severity and solid load, increased hydrochar carbon content while drastically reduced the oxygen fraction. The reason was probably related to promoted dehydration and decarboxylation. As result, carbon and energy yields were respectively increased by 26.1 % and 27.0 %, on average. The energy balance outcomes showed that the energy recovery rose up to 8 times by recycling PW compared to phases with deionized water as HTC solvent. [Display omitted] • Hydrochar recovery enhancement is obtained by solvent recirculation. • Intense synergistic effects in hydrochar formation occur at low temperatures. • Dehydration and decarboxylation are promoted by solvent recycling. • Hydrochar carbon retention is increased by 6.2 % after recirculation at 180 °C. • Process water recirculation improves the conversion energy efficiency. [ABSTRACT FROM AUTHOR]

This paper makes projections of the theoretical and technical potentials of bioenergy supply for 2050. The projections consider changes in available land for bioenergy and food for the global demand and advancements in yield, productivity, expansion of bio-waste recovery, and energy conversion. We present a literature review on projections. We introduced a novel logical and transparent forecasting model. Three future scenarios were established: business as usual (BUS), optimistic trends (OPT), and full adaptation response (FAR). The projection is carried out based on four adjusting factors. An uncertainty analysis was carry-out based on a Monte-Carlo method. Projections of bioenergy production in 2050 were compared with other projections in the literature. The FAR scenario showed that it would be possible to produce twenty-one times the current primary bioenergy supply and to even supply all global primary energy demand in 2050, mostly by energy crops. The assumptions adopted for the BUS and OPT scenarios make their projections more likely. Therefore, the contribution of bioenergy in the global energy matrix is expected to be between 64 and 313 EJ (7.5%–37%) in 2050. There would be a significant change in the composition of the bioenergy supply from today's mostly firewood to energy crops and biowastes. The technical potential for fuel and electric power mostly follow the supply trends for primary bioenergy (theoretical). The potential avoided greenhouse emissions are estimated. The heuristics and the level of transparency of the novel model will allow adjustments and exploration of other scenarios as time passes. • Novel model for projections of the potential of global primary bioenergy supply. • Bioenergy supply potential is shown for 11 different groups of biomass. • Global primary bioenergy supply could increase up to 6 times by 2050 (37% of demand). • Full adaptation response scenario could meet 100% of the global energy demand. • Bioenergy can play a major role in the global energy supply. [Display omitted] [ABSTRACT FROM AUTHOR]

Supercritical water oxidation (SCWO) is an effective, promising technology for destroying almost all kinds of organic waste with the advantage of high removal efficiency and low residence time, and without producing pollutant byproduct. The chemical energy of organic pollutants can be considered as an emerging renewable energy source. As a high-temperature and pressure process, an immense energy demand is required in the pressurization and preheating sections. On the other side, the reactor effluent has a great potential for energy recovery because of the great amount of heat released during the SCWO reaction combined with the previous energy input. Thus, SCWO is not only an organic waste treatment process but also an energy conversion and utilization system. The application of SCWO has been extended to the clean, efficient utilization of low-quality fuels such as high-sulfur coal, heavy oils, and biomass instead of conventional combustion, hydrothermal spallation drilling in geothermal energy production, and heavy oil recovery. However, energy consumption cost is still rather high in the actual process due to insufficient equipment performance, unreasonable energy system integration, and selection of an anti-corrosion and salt plugging reactor. Thus, a systematic, in-depth analysis on energy conversion and utilization in SCWO is conducted for the first time in the paper. The mechanism of exergy destruction analyses indicates that reducing enthalpy change and energy level difference are critical to reducing energy consumption. Suggestions on improving energy efficiency are proposed in the preheating stage, chemical exergy release, and reactor design. [Display omitted] • Energy conversion and utilization in each stage of an SCWO system are analyzed. • Research methods and evaluation parameters for energy utilization are summarized. • Main factors affecting energy efficiency are summarized and analyzed. • The mechanism of exergy destruction is analyzed to reduce energy consumption. • Suggestions on improving energy efficiency are proposed. [ABSTRACT FROM AUTHOR]