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Start Over Author "Ball, Richard J." Journal biochemistry
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1. ESEEM studies of substrate water and small alcohol binding to the oxygen-evolving complex of photosystem II during functional turnover

Author

Ahrling, Karin A., Evans, Mike C.W., Nugent, Jonathan H.A., Ball, Richard J., and Pace, Ron J.

Subjects
Photosynthesis -- Research, Water -- Chemical properties, Alcohols -- Chemical properties, Protein binding -- Analysis, Biological sciences, Chemistry
Abstract

The first examination of exchangeable proton and MeOH interactions with the Mn catalytic cluster in photosystem II is described, under functional flash turnover conditions, using (super 2)H ESEEM spectroscopy on the S2 and S0 multiline states. It is observed that a hyperfine resolved multiline S0 signal could be seen in the presence of D2O, the hyperfine structure of which depended on the presence or absence of methanol (MeOH).

Published
2006

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