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Start Over Author "Núria Vàzquez" Journal beilstein journal of organic chemistry
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1. Copper-catalyzed O-alkenylation of phosphonates

Author

Nuria Vázquez-Galiñanes, Mariña Andón-Rodríguez, Patricia Gómez-Roibás, and Martín Fañanás-Mastral

Subjects
alkenylation, copper, c(sp2)–o bond formation, hypervalent iodine, phosphonates, Science, Organic chemistry, QD241-441
Abstract

Copper catalysis allows the direct oxygen alkenylation of dialkyl phosphonates with alkenyl(aryl)iodonium salts with selective transfer of the alkenyl group. This novel methodology proceeds with a wide range of phosphonates under mild conditions and gives straightforward access to valuable enol phosphonates in very good yields.

Published
2020
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