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The low-low-temperature electrostatic precipitator (LLT-ESP) is considered one of the mainstream technological approaches for achieving ultra-low ash emissions and has already been applied in many coal-fired power plants. Particulate matter and SO3 can both be removed by LLT-ESP. However, the removal performance of SO3 is relatively lower than that of particulate matter, which is caused by the condensation characteristics of SO3. In this paper, the condensation characteristics of SO3 were investigated on a simulated experimental system, and several measurement and characteristic methods were used to investigate mechanisms. After reducing the flue gas temperature with a heat exchanger, the size distribution of particulate matter, the mass concentration of SO3 on different sizes of particulate matter, as well as the microscopic morphology and elemental composition of particulate matter, were all experimentally studied. The results indicate that gaseous SO3 transformed into a liquid phase by heterogeneous or homogeneous condensation and then adhered to the surface of particulate matter through nucleation–condensation, collision–coalescence, and adsorption reactions. Furthermore, the removal efficiency of SO3 in LLT-ESP was also investigated under various conditions, such as ash concentration and flue gas temperature drop, suggesting that a higher ash concentration and a more significant temperature drop were beneficial for improving SO3 removal efficiency. Nevertheless, it is worth noting that the impact was limited by a further increase in ash concentration and a drop in flue gas temperature. [ABSTRACT FROM AUTHOR]

Condensable particulate matter (CPM) is different from filterable particulate matter (FPM), which could escape from air pollution control devices (APCDs) and pose a great threat to the environment and human health. Thus, modeling and experimental studies were conducted on CPM particle behavior and removal, in a cold electrode electrostatic precipitator (CE−ESP) coupled with a electric field, temperature field and concentration field. A multi−field force coupling model was then established that was based on the mechanical behavior of particles inside the CE−ESP. The results showed that temperature field was beneficial to depositing small size particles and that, the greater the temperature gradient, the higher CPM's removal efficiency. While the electric field tended to gather larger size particles, the greater the voltage provided, the higher the removal efficiency for CPM and FPM. In the multi−field, the augmented coagulation and the removal efficiencies of both CPM and FPM increased significantly, reaching 89% and 98%, respectively. Subsequently, experiments were conducted by a self−made CE−ESP device, which showed the removal efficiencies of CE−ESP of a CPM in a multi−field were 91% and 81% for a coal−fired power plant and a waste incineration plant, respectively. This research could make a great contribution to CPM condensation, aggregation and removal. [ABSTRACT FROM AUTHOR]