1. Regulation of dewetting and morphology evolution in spin-coated PS/PMMA blend films via graphene-based Janus nanosheets
- Author
-
Haibin Cai, Botuo Zheng, Deqin Zhu, Yaqiong Wu, Ruth Cardinaels, Paula Moldenaers, Zhuofan Shen, Yu Sheng, Hu Zhu, Kai Yu, Huagui Zhang, Group Anderson, Processing and Performance, and ICMS Affiliated
- Subjects
Interfacial compatibilization ,Morphology regulation ,Pickering emulsion polymerization ,General Physics and Astronomy ,Surfaces and Interfaces ,General Chemistry ,PS/PMMA blend film ,Condensed Matter Physics ,Janus particle ,Surfaces, Coatings and Films ,Graphene oxide - Abstract
Spin-coated blend films with complex phase-separated morphology find broad applications while precise tailoring of the morphology is still challenging. In this study, graphene oxide (GO)-based Janus nanosheets were synthesized by interfacial polymerization in a GO nanosheet stabilized Pickering emulsion with polystyrene (PS) and poly(hydroxyethyl methacrylate) synchronously being grafted to the GO nanosheet from the oil and water sides. The Janus nanosheets make the morphology of spin-coated PS/poly(methyl methacrylate)(PMMA) blend films tunable over the full height of the film until the substrate as their preferential assembly at the PS/PMMA interface and attachment on the glass substrate drive the top PS phase to migrate towards the substrate and the bottom PMMA phase to dewet from the substrate towards the air. By varying blend composition and Janus nanosheet loading, morphologies are readily transformed from a PS network on top of PMMA to PS droplets in the PMMA matrix and from PS encapsulated by PMMA to PMMA cavities in the PS network, etc.. This enables generating thin films with various morphologies ranging from a flat surface to cavity-network structures, droplet-matrix structures or bi-continuous structures, etc. at will. Moreover, the morphologies trapped by jammed nanosheets at the interface are super stable against further evolution upon annealing.
- Published
- 2023