1. Separation of no-carrier-added 66,67Ga produced in heavy ion-induced cobalt target using alginate biopolymers
- Author
-
Anupam Banerjee, Dalia Nayak, and Susanta Lahiri
- Subjects
inorganic chemicals ,Radiation ,Calcium alginate ,Period (periodic table) ,Alginates ,Hexuronic Acids ,Radiochemistry ,chemistry.chemical_element ,Gallium Radioisotopes ,Germanium ,Cobalt ,Chemical Fractionation ,Matrix (chemical analysis) ,chemistry.chemical_compound ,Biopolymers ,Glucuronic Acid ,chemistry ,Heavy Ions ,Gallium ,Arsenic ,FOIL method ,Nuclear chemistry - Abstract
Heavy ion activation of natural cobalt foil with 84 MeV 12 C results in the formation of no-carrier-added (nca) 66,67 As radionuclides, along with their corresponding decay products, 66,67 Ge and 66,67 Ga, in the matrix. Because arsenic and germanium radionuclides are short-lived, after a cooling period of 10 h only nca gallium radionuclides remain in the matrix. We attempted to separate the nca gallium radionuclides from the target matrix cobalt by biopolymeric calcium alginate (CA) and Fe-doped calcium alginate (Fe-CA) beads. A complete separation has been achieved by adsorbing 66,67 Ga and a lesser amount of bulk cobalt at pH 3 on Fe-CA beads, followed by desorbing cobalt from the beads with 0.4 M NaNO 2 .
- Published
- 2007