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Artificial intelligent skins hold the potential to revolutionize artificial intelligence, health monitoring, soft robotics, biomedicine, flexible, and wearable electronics. Present artificial skins can be characterized into electronic skins ( e-skins) that convert external stimuli into electrical signals and photonic skins ( p-skins) that convert deformations into intuitive optical feedback. Merging both electronic and photonic functions in a single skin is highly desirable, but challenging and remains yet unexplored. We report herein a brand-new type of artificial intelligent skin, an optoelectronic skin ( o-skin), which combines the advantages of both e-skins and p-skins in a single skin device based on one-dimensional photonic crystal-based hydrogels. Taking advantage of its anisotropic characteristics, the resulting o-skin can easily distinguish vector stimuli such as stress type and movement direction to meet the needs of multi-dimensional perception. Furthermore, the o-skin also demonstrates advanced functions such as full-color displays and intelligent response to the environment in the form of self-adaptive camouflage. This work represents a substantial advance in using the molecular engineering strategy to achieve artificial intelligent skins with multiple anisotropic responses that can be integrated on the skin of a soft body to endow superior functions, just like the natural organisms that inspire us.