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We demonstrate high efficiency white organic light-emitting devices with two adjacent emissive layers each doped with three phosphorescent emitters (blue, green, and red). Efficient charge and exciton confinement is realized by employing charge transport layers with high triplet energy, leading to a maximum external quantum efficiency of (19±1)%. Using the p-i-n device structure, we have achieved a peak power efficiency of (40±2) lm/W and (36±2) lm/W at 100 cd/m2, a color rendering index of 79, and Commission Internationale de L’Eclairage coordinates of (0.37, 0.40) for the white light emission. [ABSTRACT FROM AUTHOR]

We report on very high efficiency deep-blue phosphorescent organic light-emitting devices (PHOLEDs) based on iridium(III) bis(4′,6′-difluorophenylpyridinato)tetrakis(1-pyrazolyl)borate (FIr6). Dual emissive layers consisting of an N,N′-dicarbazolyl-3,5-benzene layer doped with 4 wt % FIr6 and a p-bis(triphenylsilyly)benzene layer doped with 25 wt % FIr6 were employed to maximize exciton generation on FIr6 molecules. Combined with the p-i-n device structure, we achieved a low turn-on voltage of 3.2 V and very high power efficiencies of 25±2 lm/W at 100 cd/m2 and 20±2 lm/W at 1000 cd/m2 for such deep-blue PHOLEDs with peak emission at a wavelength of 458 nm. [ABSTRACT FROM AUTHOR]