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AgBiSe2 is a promising thermoelectric (TE) candidate because of its intrinsically low thermal conductivity (κ = 0.4–0.5 W K−1 m−1 at ∼770 K) and optimal n-type carrier concentration (5.85 × 1018 cm−3 at 300 K). However, its TE figure of merit (ZT) is still low (0.3 at ∼770 K). Therefore, it is necessary to further improve its ZT. In this work, the solid solutions (AgBiSe2)1−x(Ag2Te)x (x = 0–0.125) have been designed through simple alloying Ag2Te inspired by the entropy engineering concept, and the TE performance has been further regulated. The analyses show that the exothermic effects related to α/β and β/γ phase transitions weaken, and the transition temperature of β/γ decreases as the Ag2Te content increases, which indicates the stabilization of the cubic γ-phase at high temperatures. Aside from that, the power factor (PF) enhances from 2.91 μW/cm K2 (x = 0) to 3.49 μW/cm K2 (x = 0.075), and at the same time, the lattice thermal conductivity reduces from 0.3 W K−1 m−1 to 0.1 W K−1 m−1 at ∼760 K. This directly improves the TE performance with the highest ZT value of 1.0, which is almost double that of the pristine AgBiSe2. The result suggests that the entropy engineering is a very effective screening method in thermoelectrics. [ABSTRACT FROM AUTHOR]

We synthesized the solid solutions CuGa1-xInxTe2 (x = 0-1.0) by isoelectronic substitution of element In (Ga) for Ga(In) in the CuMTe2 (M = Ga, In) lattices and examined their thermoelectric properties. The structure upon substitution provides much high Seebeck coefficient (α), relatively low thermal (κ), and electrical conductivity (σ). AT 701 K, the α, σ, and κ are 283.15 µV K-1, 1.15 × 104 Ω-1 m-1, and 0.71 W m-1 K-1, respectively, for CuGa0.36In0.64Te2, which give the figure of merit (ZT) of 0.91, about two times those of the mother compounds CuGaTe2 and CuInTe2. This material holds great application perspectives at intermediate temperatures. [ABSTRACT FROM AUTHOR]