Search

Whether it is glass, ceramics, cement, or concrete, minimizing thermal conduction through disordered materials is a determining factor when it comes to reducing the energy consumption of cities. In this work, we explore underlying physical processes involved in thermal conduction through the disordered glue of cement, calcium-silicate-hydrates (CSH). We find that at 300 K, phonon-like propagating modes in accordance with the Boltzmann transport theory, propagons, account for more than 30% of the total thermal conductivity, while diffusons, described via the Allen-Feldman theory, contribute to the remainder. The cumulative thermal conductivity proves to be close to both equilibrium molecular dynamics calculations and experimental values. These findings help us establish different strategies, such as localization schemes (to weaken diffusons) and scattering mechanisms (to constrain propagons), for reduction of thermal conductivity of CSH without sacrificing its mechanical properties. [ABSTRACT FROM AUTHOR]