1. Cavity-enhanced photothermal spectroscopy: dynamics, sensitivity, and spatial resolution
- Author
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E. C. Benck, Hans A. Schuessler, Z. Rong, Z. C. Tang, and Shih Hsun Chen
- Subjects
Materials science ,Photothermal spectroscopy ,business.industry ,Materials Science (miscellaneous) ,Thermal diffusivity ,Laser ,Industrial and Manufacturing Engineering ,law.invention ,Absorbance ,Optics ,law ,Continuous wave ,Business and International Management ,Spectroscopy ,business ,Absorption (electromagnetic radiation) ,Power density - Abstract
The spectrally resolved low-level absorption of thin films and of solid and liquid surfaces was measured by cavity-enhanced photothermal spectroscopy. The technique is ultrasensitive and can determine surfacespecific absorbances alpha(omega) ~ 10(-6) at a power density of 10(4)W/cm(2). Both cases of continuous wave and modulated laser light absorption were studied experimentally and are interpreted theoretically. It is shown that it is possible to achieve a spatial resolution of absorbance variations in the few-micrometer range. The thermal diffusivity can also be simultaneously measured by observing the time evolution of the surface temperature during laser irradiation.
- Published
- 2010