Search

Abstract: The Lorraine Triassic Sandstone Aquifer (LTSA), which has already been the subject of a chemical and radioisotopic study (1979), is used to investigate the impacts of 20a of large scale pumping on baseline water quality. In parallel, new sampling of the aquifer (2001) provides new inorganic geochemical data (including trace elements) that allow improving the knowledge of baseline conditions and hydrochemical functioning of a major sandstone aquifer. The good correlation between 14C activities, temperature and depth along the main flow line indicate regular downgradient trends and possible water stratification. Unreactive tracers, mainly stable isotope ratios 18O and 2H, as well as C isotopes are used to define a timescale for the aquifer, showing two groups of groundwater, namely of modern and Holocene age, and late Pleistocene age, with a mixing zone. Baseline quality is then represented by a wide range of concentrations, mainly the result of time-dependent water–rock interaction, as already observed elsewhere in Triassic sandstone aquifers. Some trace elements such as Li, Rb, Cs, which are not limited by solubility constraints, show linear trends. During saturated flow downgradient, the chemistry is also specifically characterised by a regular increase in Na and Cl (and locally SO4) as a result of evaporite dissolution related to overlying or basement limits. The aquifer is mostly oxidising with a redox boundary marked by U decrease, some 40km from outcrop. Groundwater abstraction since the 1970s has created a strong lowering (10–150m) of the water table, especially from 1970 to 1980. Based on nine boreholes, previously sampled in 1979, a decreasing evolution in radiocarbon content of the TDIC, together with significant evolution of 18O content, indicate that old groundwater has moved upgradient. The major difference in terms of baseline evolution is observed using Cl and Na concentration and, locally, SO4, indicating an increasing influence of water circulation involving overlying or basement formations, or of mixing with Permian waters. From the point of view of aquifer management, the perceptible NO3 increase could provide information on the progress of any contamination under the aerobic conditions. In addition, the few key elements, indicators of disequilibrium, related to overlying or deep waters, should be included in regular monitoring programmes. [Copyright &y& Elsevier]