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Sebacate (SB) molecules were incorporated into Ca Al layered double hydroxides (CaAL-LDH) using a hydrothermal method. The resulting products underwent characterization through X-ray diffraction, infrared spectroscopy, and scanning electron microscopy. To investigate the release kinetics and thermodynamics of the corrosion inhibitor, total organic carbon analysis (TOC) was employed. A comparison was made with CaAl-LDH prepared without corrosion inhibitors, in which nitrates were the primary anions within the layered clay structure. An assessment of anion exchange between nitrates and chlorides was conducted using total nitrogen analysis (TN). The SB anion comprised approximately 49.2% of the total dried powder synthesized, with a maximum release efficiency of around 86.7% fitting a Langmuir model. For the evaluation of the corrosion inhibition effect on steel surfaces, electrochemical impedance spectroscopy, potentiodynamic polarization, and scanning vibrating electrode technique were employed. The corrosion inhibition impact was ascribed to the liberation of SB anions from the CaAl-LDH pigments, accompanied by alkalinization stemming from partial particle dissolution. Additionally, the incorporation of organic molecules notably enhanced the stability of pigments in aqueous solutions compared to similar ones hosting nitrates. These findings suggested that CaAl-LDH pigments have potential as nanocontainers for organic inhibitors, showing promising prospects in the field of corrosion research. [Display omitted] • Synthesis of CaAl-LDHs particles with sebacate intercalated. • Sebacate anionic exchange with chlorides is efficient at 86.7%. • Organic molecule intercalation gives improved stability in water. • Steel corrosion protection is provided by chloride trapping and inhibitor release. [ABSTRACT FROM AUTHOR]