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Start Over Author "Michael Kemmer" Journal angewandte chemie international edition
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1. Mechanism of Reduction of Diphenylacetylene by Metallic Lithium

Author

Michael Kemmer, Hsien C. Wang, Adalbert Maercker, Michael Szwarc, and Da-Hai Dong

Subjects
chemistry.chemical_compound, chemistry, Metallic lithium, Kinetics, chemistry.chemical_element, Lithium, General Chemistry, Photochemistry, Diphenylacetylene, Catalysis, Cis–trans isomerism, Adduct
Abstract

A zero-order reaction converts cis-dilithiostilbene (1), formed upon reduction of diphenylacetylene by lithium, into the trans isomer 2. The cis-monolithiated adduct acts as a catalyst.

Published
1998
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