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Your search keyword '"Inigo J"' showing total 5 results
Start Over Author "Inigo J" Journal angewandte chemie international edition
5 results on '"Inigo J"'

1. Hybrid Organic-Inorganic Rotaxanes, Including a Hetero-Hybrid [3]Rotaxane Featuring Two Distinct Heterometallic Rings and a Molecular Shuttle

Author

Timco, Grigore A., primary, Fernandez, Antonio, additional, Kostopoulos, Andreas K., additional, Charlton, Jodie F., additional, Lockyer, Selena J., additional, Hailes, Thomas R., additional, Adams, Ralph W., additional, McInnes, Eric J. L., additional, Tuna, Floriana, additional, Vitorica-Yrezabal, Inigo J., additional, Whitehead, George F. S., additional, and Winpenny, Richard E. P., additional

Published
2018
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5. [CrF(O2C tBu)2]9: Synthesis and Characterization of a Regular Homometallic Ring with an Odd Number of Metal Centers and Electrons.

Author

Woolfson, Robert J., Timco, Grigore A., Chiesa, Alessandro, Vitorica-Yrezabal, Inigo J., Tuna, Floriana, Guidi, Tatiana, Pavarini, Eva, Santini, Paolo, Carretta, Stefano, and Winpenny, Richard E. P.

Subjects
CHEMICAL synthesis, AMINES, INELASTIC neutron scattering, ELECTRONS, RING formation (Chemistry)
Abstract

The first regular homometallic ring containing an odd number of metal centers is reported. The ring was synthesized by means of amine-templated self-assembly. Extensive physical characterization studies, including magnetic measurements, powder inelastic neutron scattering (INS), and DFT calculations, show that the molecule has a near perfect match to the expected behavior for a frustrated system with the lowest energy pair of S=1/2 spin states separated by only 0.1 meV (0.8 cm−1). [ABSTRACT FROM AUTHOR]

Published
2016
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