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Start Over Author "Clarke, Matthew L." Topic rhodium Journal angewandte chemie international edition

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1. High iso Aldehyde Selectivity in the Hydroformylation of Short‐Chain Alkenes.

Author

Iu, Leo, Fuentes, José A., Janka, Mesfin E., Fontenot, Kevin J., and Clarke, Matthew L.

Subjects
*ALDEHYDES, *HYDROFORMYLATION, *ALKENES, *RHODIUM compounds, *PHOSPHOLANES
Abstract

The hydroformylation of propene to give predominantly iso‐butanal has been achieved; class‐leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos‐biphenols and unusual solvent systems are the key to the selectivity observed. [ABSTRACT FROM AUTHOR]

Published
2019
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