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Start Over Author "Zhao, Jincai" Topic photochemistry Journal angewandte chemie international edition
1 results on '"Zhao, Jincai"'

1. Concerted Two-Electron Transfer and High Selectivity of TiO2 in Photocatalyzed Deoxygenation of Epoxides.

Author

Li, Yue, Ji, Hongwei, Chen, Chuncheng, Ma, Wanhong, and Zhao, Jincai

Subjects
PHOTOCHEMICAL research, PHOTOCATALYTIC oxidation, DEOXYGENATION, EPOXY compounds, TITANIUM dioxide, ISOPROPYL alcohol
Abstract

No two ways about it: In the photocatalytic deoxygenation of epoxides, the TiO2 particle concertedly transfers two stored electrons to generate a carbanion intermediate, which dissociates to the alkene product. This pathway ensures the higher alkene and stereoselectivity of the photocatalytic deoxygenation than those involving a single‐electron transfer. [ABSTRACT FROM AUTHOR]

Published
2013
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