1. Layer‐Defining Strategy to Grow Two‐Dimensional Molecular Crystals on a Liquid Surface down to the Monolayer Limit.
- Author
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Yao, Jiarong, Zhang, Yu, Tian, Xinzi, Zhang, Xiali, Zhao, Huijuan, Zhang, Xiaotao, Jie, Jiansheng, Wang, Xinran, Li, Rongjin, and Hu, Wenping
- Subjects
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LIQUID crystals , *LIQUID surfaces , *CRYSTAL surfaces , *ORGANIC semiconductors , *BAND gaps , *MONOMOLECULAR films , *MOLECULAR crystals , *SURFACE tension - Abstract
Two‐dimensional molecular crystals (2DMCs) open a new door for the controllable growth of 2D materials by molecular design with a energy gap and solution processability. However, the growth of 2DMCs with defined molecular layers remains full of challenges. Herein, we report a novel method to produce various 2DMCs with a defined number of molecular layers. When the surface tension and viscosity are tuned to control the spreading of the solution on the liquid surface, large‐area quasi‐freestanding 2DMCs from bulk size down to the monolayer limit are obtained, which makes it possible to probe the intrinsic layer‐dependent optoelectronic properties of organic semiconductors down to the physical limit, and paves the way for the application of 2DMCs in new optoelectronic devices and technologies. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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