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2. Coordinative Approach to Mediated Electron Transfer: Ruthenium Complexed to Native Glucose Oxidase.

Author

Ryabova ES, Goral VN, Csöregi E, Mattiasson B, and Ryabov AD

Abstract

Catalytically and electrocatalytically very active and stable are the complexes Ru(LL)-GO, which are extremely readily accessible from glucose oxidase (GO) and the Ru II complexes cis-[Ru(LL) 2 Cl 2 ] (LL=bpy, phen). These provide an unprecedentedly high amplification coefficient I/I o (see cyclic voltammograms) even at high scan rates and, correspondingly, very high rates of intramolecular electron transfer., (© 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.)

Published
1999
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