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Start Over Author "de Kanter FJ" Journal angewandte chemie (international ed. in english)
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3. Olefin Cycloadditions of the Electrophilic Phosphinidene Complex

Author

Wit, van Eijkel GT, de Kanter FJ, Schakel, Ehlers, Lutz, Spek, and Lammertsma

Abstract

Highly strained methylenephosphiranes are formed in the reaction of the new electrophilic phosphinidene complex [iPr(2)N-P=Fe(CO)(4)] with allenes. Remarkably, reaction with diallenes at 0 degrees C also leads to a phosphirane, which rearranges upon warming to room temperature to a bis-isopropylidenephospholene (see scheme).

Published
1999

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