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Start Over Author "Paul A. Lummis" Journal angewandte chemie (international ed. in english)
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1. Accessing zinc monohydride cations through coordinative interactions

Author

Michael J. Ferguson, Eric Rivard, Robert McDonald, Mohammad R. Momeni, Paul A. Lummis, Mark Miskolzie, Alex Brown, and Melanie W. Lui

Subjects
Hydrosilylation, Hydride, chemistry.chemical_element, Homogeneous catalysis, Zinc hydride, General Medicine, General Chemistry, Zinc, Photochemistry, Catalysis, chemistry.chemical_compound, chemistry, Nucleophile, Polymer chemistry, Electrophile, Carbene
Abstract

We present isolable examples of formal zinc hydride cations supported by N-heterocyclic carbene (NHC) donors, and investigate the dual electrophilic and nucleophilic (hydridic) character of the encapsulated [ZnH](+) units by computational methods and preliminary hydrosilylation catalysis.

Published
2014

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