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3. Experimental and Computational Studies of the Copper Borate Complexes [(NHC)Cu(HBEt3)] and [(NHC)Cu(HB(C6F5)3)].

Author

Collins, Lee R., Rajabi, Nasir A., Macgregor, Stuart A., Mahon, Mary F., and Whittlesey, Michael K.

Subjects
*COPPER, *LIGANDS (Chemistry), *LEWIS acids, *CARBENES, *ELLIPSOIDS
Abstract

The synthesis of the Cu-borate complexes [(6Mes)Cu(HBR3)] featuring the unusual [HBEt3]− ( 5) and [HB(C6F5)3]− ( 6) ligands is described. Experimental and computational studies show both compounds feature a direct Cu-H interaction, but that while 5 is two-coordinate, 6 displays an additional, stabilizing Cu-Cipso(C6F5) interaction. [ABSTRACT FROM AUTHOR]

Published
2016
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4. Experimental and Computational Studies of the Copper Borate Complexes [(NHC)Cu(HBEt3)] and [(NHC)Cu(HB(C6F5)3)].

Author

Collins, Lee R., Rajabi, Nasir A., Macgregor, Stuart A., Mahon, Mary F., and Whittlesey, Michael K.

Subjects
COPPER, LIGANDS (Chemistry), LEWIS acids, CARBENES, ELLIPSOIDS
Abstract

The synthesis of the Cu-borate complexes [(6Mes)Cu(HBR3)] featuring the unusual [HBEt3]− ( 5) and [HB(C6F5)3]− ( 6) ligands is described. Experimental and computational studies show both compounds feature a direct Cu-H interaction, but that while 5 is two-coordinate, 6 displays an additional, stabilizing Cu-Cipso(C6F5) interaction. [ABSTRACT FROM AUTHOR]

Published
2016
Full Text
View/download PDF

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